Liquid-Phase Ethyl Benzene Oxidation Catalysed by Manganese Salts

1999 ◽  
Vol 3 (6) ◽  
pp. 400-403 ◽  
Author(s):  
Tatiana V. Bukharkina ◽  
Olga S. Grechishkina ◽  
Nikolai G. Digurov ◽  
Nadezhda V. Krukovskaya
2003 ◽  
Vol 7 (2) ◽  
pp. 148-154 ◽  
Author(s):  
Tatiana V. Bukharkina ◽  
Olga S. Grechishkina ◽  
Nikolai G. Digurov ◽  
Nadezhda V. Krukovskaya

2021 ◽  
pp. 118456
Author(s):  
Sayyed Mahdi Hosseini ◽  
Mehran Ghiaci ◽  
Sergei A. Kulinich ◽  
Wilfried Wunderlich ◽  
Hassan S. Ghaziaskar ◽  
...  

2021 ◽  
Author(s):  
Subhashree Mishra ◽  
Rajaram Bal ◽  
Simon Watre Sangma ◽  
R. K. Dey

In this study, liquid phase oxidation of ethyl benzene to acetophenone was widely investigated using a new recyclable supported catalyst of CuO–nanoparticles impregnated over activated red–mud (CuO_AARM). The catalyst was...


1956 ◽  
Vol 59 (6) ◽  
pp. 654-657
Author(s):  
Akoto Kobayashi ◽  
Kazuo Sadakata ◽  
Saburo Akiyoshi

2019 ◽  
Vol 43 (18) ◽  
pp. 6921-6931 ◽  
Author(s):  
Sheyda Nilforoushan ◽  
Mehran Ghiaci ◽  
Sayyed Mahdi Hosseini ◽  
Sophie Laurent ◽  
Robert N. Muller

A hybrid structure g-C3N4–rGO with honeycomb units was prepared for immobilizing Pd nanoparticles by a simple wet impregnation method.


1995 ◽  
Vol 155 (1) ◽  
pp. 158-162 ◽  
Author(s):  
T. Ohtani ◽  
S. Nishiyama ◽  
S. Tsuruya ◽  
M. Masai

ACS Catalysis ◽  
2012 ◽  
Vol 2 (7) ◽  
pp. 1421-1424 ◽  
Author(s):  
Vera P. Santos ◽  
Jasper J.W. Bakker ◽  
Michiel T. Kreutzer ◽  
Freek Kapteijn ◽  
Jorge Gascon

2004 ◽  
Vol 82 (11) ◽  
pp. 1597-1605 ◽  
Author(s):  
Takahiro Kitamura ◽  
Hiroshi Kanzaki ◽  
Rei Hamada ◽  
Satoru Nishiyama ◽  
Shigeru Tsuruya

The liquid-phase catalytic oxidation of benzene was carried out under mild reaction conditions over Cu-impregnated zeolite catalysts (Cu/NaX, Cu/HX, Cu/NaY, Cu/HY, Cu/NaZSM-5, Cu/HZSM-5, Cu/Namordenite, Cu/Hmordenite, and Cu/Hbeta) using both molecular oxygen and ascorbic acid as the oxidant and the reducing reagents, respectively. Phenol was exclusively produced as the oxidation product and no other product was detected. Among the catalysts tested in this study, the Cu/HY catalyst had the highest activity for phenol formation. H-type zeolites were more effective supports for phenol formation than the corresponding Na-type ones. The yield of phenol was found to increase with the simultaneous increase in the amounts of both the supported Cu and the added ascorbic acid. The Cu species supported on HY began to elute as Cu2+ species in the solvent from the HY support with the initiation of the oxidation of benzene. The dissolved Cu2+ species were reduced to form precipitated Cu1+ species during the benzene oxidation. The homogeneous Cu species dissolved from the Cu/HY catalyst were thus suggested as mainly contributing to the phenol formation. The precipitated Cu1+ species that had no activity for the benzene oxidation were found to be regenerated in their oxidation activity toward phenol formation by calcination of the Cu1+ species in flowing air, although parts of the Cu species were found to be converted to aggregated CuO during the calcination.Key words: supported copper catalysts, zeolite, oxidation, benzene, phenol, oxygen, ascorbic acid.


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