P−C Bond Splitting Reactions in Ruthenium(II) Complexes of Binap and MeO−Biphep Using CF3SO3H and HBF4. A Novel Ru−F−H Interaction

2000 ◽  
Vol 19 (3) ◽  
pp. 309-316 ◽  
Author(s):  
Carolien J. den Reijer ◽  
Michael Wörle ◽  
Paul S. Pregosin
Keyword(s):  
Bond Splitting

scholarly journals STUDY ON THE BOND SPLITTING STRENGTH OF SHEATHS FOR A PRECAST CONCRETE SYSTEM

1995 ◽  
Vol 60 (473) ◽  
pp. 137-148
Author(s):  
Rodolfo YANEZ ◽  
Juan Jose CASTRO ◽  
Teruaki YAMAGUCHI ◽  
Hiroshi IMAI
Keyword(s):  
Precast Concrete ◽  
Concrete System ◽  
Splitting Strength ◽  
Bond Splitting

Hydrogenation of cinnamyl methyl ether and allylbenzene on palladium catalysts

1987 ◽  
Vol 52 (4) ◽  
pp. 1015-1020 ◽  
Author(s):  
Libor Červený ◽  
Ivo Paseka ◽  
Eva Fialová ◽  
Vlastimil Růžička
Keyword(s):  
Double Bond ◽  
Solvent Effect ◽  
Benzene Ring ◽  
Methyl Ether ◽  
Atmospheric Pressure ◽  
Palladium Catalysts ◽  
Polar Medium ◽  
Adsorbed Molecules ◽  
Ionic Nature ◽  
Bond Splitting

The hydrogenation of cinnamyl methyl ether and allylbenzene in hexane and acetone at 20 °C and atmospheric pressure of hydrogen has been studied on eight palladium catalysts. The hydrogenation of cinnamyl methyl ether is accompanied by C-O bond splitting giving rise to propylbenzene and methanol, the hydrogenation of allylbenzene is associated with the isomerization of the double bond resulting in its conjugation with the benzene ring. A marked solvent effect on the selectivity of hydrogenation of cinnamyl methyl ether has been observed and ascribed to the effect of solvated protons on the adsorbed molecules of the ether which is promoted by polar medium. The solvent effect on the isomerization of allylbenzene during the hydrogenation is little pronounced, which suggests that this reaction is not of ionic nature.

Protonation and NMR studies on 13C-acetate enriched Ru(OAc)2(Binap). Acetate as a source of water in PC bond splitting

2002 ◽  
Vol 330 (1) ◽  
pp. 155-160 ◽  
Author(s):  
T.J. Geldbach ◽  
C.J. den Reijer ◽  
M. Wörle ◽  
P.S. Pregosin
Keyword(s):  
Nmr Studies ◽  
Bond Splitting

scholarly journals Efficient C–C bond splitting on Pt monolayer and sub-monolayer catalysts during ethanol electro-oxidation: Pt layer strain and morphology effects

2014 ◽  
Vol 16 (35) ◽  
pp. 18866-18876 ◽  
Author(s):  
Rameshwori Loukrakpam ◽  
Qiuyi Yuan ◽  
Valeri Petkov ◽  
Lin Gan ◽  
Stefan Rudi ◽  
...  
Keyword(s):  
Electro Oxidation ◽  
Monolayer Catalysts ◽  
Bond Splitting
Sign in / Sign up

Export Citation Format

Share Document