Relative Binding Energies of Tertiary Phosphine Ligands to the Cp*RuOCH2CF3(Cp* = η5-C5Me5) Moiety

1996 ◽  
Vol 15 (15) ◽  
pp. 3456-3462 ◽  
Author(s):  
Chunbang Li ◽  
Lubin Luo ◽  
Steven P. Nolan ◽  
William Marshall ◽  
Paul J. Fagan
Keyword(s):  
Binding Energies ◽  
Phosphine Ligands ◽  
Tertiary Phosphine ◽  
Relative Binding

Cationic gold clusters ligated with differently substituted phosphines: effect of substitution on ligand reactivity and binding

2015 ◽  
Vol 17 (22) ◽  
pp. 14636-14646 ◽  
Author(s):  
Grant E. Johnson ◽  
Astrid Olivares ◽  
David Hill ◽  
Julia Laskin
Keyword(s):  
Ligand Binding ◽  
Lone Pair ◽  
Gold Clusters ◽  
Binding Energies ◽  
Phosphine Ligands ◽  
Strongly Correlated ◽  
P Loss ◽  
Ligand Reactivity ◽  
Cationic Gold

Loss of substituted phosphine ligands is strongly correlated with the electron donating ability of the phosphorous lone pair. The results indicate that the relative ligand binding energies increase in the order PMe3 < PPhMe2 < PPh2Me < PPh3 < PPh2Cy < PPhCy2 < PCy3.

Synthetic and thermochemical studies of fluorinated tertiary phosphine ligands R2PRf [R=Cy, Ph, iPr; Rf=CH2CH2(CF2)5CF3] in an organoiron system

2000 ◽  
Vol 300-302 ◽  
pp. 987-991 ◽  
Author(s):  
Dale C. Smith ◽  
Amy L. Klaman ◽  
Jérémie Cadoret ◽  
Steven P. Nolan
Keyword(s):  
Phosphine Ligands ◽  
Tertiary Phosphine
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