Reactions of the Schiff Base Rhodium Hydride Complex RhH(Bu4salophen) with Olefins. Observations and Mechanistic Studies

1996 ◽  
Vol 15 (6) ◽  
pp. 1697-1706 ◽  
Author(s):  
D. Joe Anderson ◽  
Richard Eisenberg
Keyword(s):  
Schiff Base ◽  
Mechanistic Studies ◽  
Hydride Complex

Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si−H Bond of Silanes

2000 ◽  
Vol 19 (15) ◽  
pp. 2896-2908 ◽  
Author(s):  
Les A. Dakin ◽  
Patricia C. Ong ◽  
James S. Panek ◽  
Richard J. Staples ◽  
Pericles Stavropoulos
Keyword(s):  
Schiff Base ◽  
Mechanistic Studies ◽  
Insertion Reactions

Mechanistic studies on the cobalt(II) Schiff base catalyzed oxidation of olefins by O2

1987 ◽  
Vol 109 (2) ◽  
pp. 374-379 ◽  
Author(s):  
Dorothy E. Hamilton ◽  
Russell S. Drago ◽  
Alan Zombeck
Keyword(s):  
Schiff Base ◽  
Mechanistic Studies ◽  
Oxidation Of Olefins ◽  
Catalyzed Oxidation

Light-promoted catalysis of nickel hydride complexes in the isomerization and hydrogenation of cis,cis-1,5-cyclooctadiene: mechanistic studies

1986 ◽  
Vol 64 (11) ◽  
pp. 2229-2231 ◽  
Author(s):  
Yuan L. Chow ◽  
Huali Li
Keyword(s):  
Double Bond ◽  
Mechanistic Studies ◽  
Hydride Complexes ◽  
Hydride Complex ◽  
Nickel Hydride ◽  
Subsequent Elimination

Xanthone-sensitized photoreduction of Ni(acac)2 in benzene under hydrogen, in the presence of cis,cis-1,5-cyclooctadiene (1,5-COD), causes isomerization and hydrogenation of the diene according to the consecutive transformation 1,5-COD → 1,4-COD → 1,3-COD → cyclooctene → cyclooctane. Evidence was provided that (i) a nickel hydride complex was generated, (ii) the sensitized excitation of this complex caused addition to the double bond, (iii) subsequent elimination caused isomerization, and (iv) triplet excited xanthone sensitized the transformations.

Intramolecular Ligand Hydroxylation:  Mechanistic Studies on the Reaction of a Copper(I) Schiff Base Complex with Dioxygen†

1998 ◽  
Vol 37 (9) ◽  
pp. 2134-2140 ◽  
Author(s):  
Sara Ryan ◽  
Harry Adams ◽  
David E. Fenton ◽  
Michael Becker ◽  
Siegfried Schindler
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Mechanistic Studies ◽  
Base Complex

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

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