Dinuclear Allylpalladium Complexes ofC2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation

2010 ◽  
Vol 29 (5) ◽  
pp. 1117-1126 ◽  
Author(s):  
Arne Ficks ◽  
Connor Sibbald ◽  
Michael John ◽  
Sebastian Dechert ◽  
Franc Meyer
Keyword(s):  
Dynamic Behavior ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Oxazoline Ligands

Chiral tetrathiafulvalene based phosphine- and thiomethyl-oxazoline ligands. Evaluation in palladium catalysed asymmetric allylic alkylation

Tetrahedron ◽  
2006 ◽  
Vol 62 (51) ◽  
pp. 11942-11947 ◽  
Author(s):  
Céline Réthoré ◽  
Isabelle Suisse ◽  
Francine Agbossou-Niedercorn ◽  
Eva Guillamón ◽  
Rosa Llusar ◽  
...  
Keyword(s):  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Oxazoline Ligands

Chiral Phosphaalkene−Oxazoline Ligands for the Palladium-Catalyzed Asymmetric Allylic Alkylation

2010 ◽  
Vol 12 (20) ◽  
pp. 4667-4669 ◽  
Author(s):  
Julien Dugal-Tessier ◽  
Gregory R. Dake ◽  
Derek P. Gates
Keyword(s):  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Palladium Catalyzed ◽  
Oxazoline Ligands

Synthesis of highly rigid phosphine–oxazoline ligands for palladium-catalyzed asymmetric allylic alkylation

2018 ◽  
Vol 16 (41) ◽  
pp. 7717-7724 ◽  
Author(s):  
Zhongxuan Qiu ◽  
Rui Sun ◽  
Dawei Teng
Keyword(s):  
Catalytic Performance ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Palladium Catalyzed ◽  
Alkylation Reactions ◽  
Stereogenic Center ◽  
Oxazoline Ligands ◽  
Excellent Catalytic Performance

Rigid phosphine–oxazoline ligands with a spirocarbon stereogenic center were developed, which exhibited excellent catalytic performance for Pd-catalyzed allylic alkylation reactions.

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