Direct Time-Resolved Study of the Kinetics of the Reaction of Silylene with Phenylsilane in the Gas Phase. Does SiH2React with the Aromatic Ring?

2009 ◽  
Vol 28 (21) ◽  
pp. 6339-6346 ◽  
Author(s):  
Rosa Becerra ◽  
J. Pat Cannady ◽  
Robin Walsh
Keyword(s):  
Gas Phase ◽  
Aromatic Ring ◽  
Time Resolved ◽  
Kinetics Of

scholarly journals Kinetics of the gas phase reaction of the Criegee intermediate CH2OO with SO2 as a function of temperature

2021 ◽  
Vol 23 (35) ◽  
pp. 19415-19423
Author(s):  
Lavinia Onel ◽  
Rachel Lade ◽  
Jennifer Mortiboy ◽  
Mark A. Blitz ◽  
Paul W. Seakins ◽  
...  
Keyword(s):  
Gas Phase ◽  
Absorption Spectroscopy ◽  
Flash Photolysis ◽  
Uv Absorption ◽  
Phase Reaction ◽  
Time Resolved ◽  
Gas Phase Reaction ◽  
Uv Absorption Spectroscopy ◽  
Kinetics Of

The kinetics of the gas phase reaction of the Criegee intermediate CH2OO with SO2 have been studied as a function of temperature in the range 223–344 K at 85 Torr using flash photolysis of CH2I2/O2/SO2/N2 mixtures at 248 nm coupled to time-resolved broadband UV absorption spectroscopy.

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