Rational Design and Synthesis of Highly Active Pincer-Iridium Catalysts for Alkane Dehydrogenation

2009 ◽  
Vol 28 (18) ◽  
pp. 5432-5444 ◽  
Author(s):  
Sabuj Kundu ◽  
Yuriy Choliy ◽  
Gao Zhuo ◽  
Ritu Ahuja ◽  
Thomas J. Emge ◽  
...  
Keyword(s):  
Rational Design ◽  
Iridium Catalysts ◽  
Alkane Dehydrogenation ◽  
Design And Synthesis ◽  
Highly Active

Rational Design of Highly Active “Hybrid” Phosphine–Phosphinite Pincer Iridium Catalysts for Alkane Metathesis

ACS Catalysis ◽  
2013 ◽  
Vol 3 (11) ◽  
pp. 2505-2514 ◽  
Author(s):  
Agnieszka J. Nawara-Hultzsch ◽  
Jason D. Hackenberg ◽  
Benudhar Punji ◽  
Carolyn Supplee ◽  
Thomas J. Emge ◽  
...  
Keyword(s):  
Rational Design ◽  
Iridium Catalysts ◽  
Highly Active ◽  
Alkane Metathesis

Highly Active Iridium Catalysts for Alkane Dehydrogenation. Synthesis and Properties of Iridium Bis(phosphine) Pincer Complexes Based on Ferrocene and Ruthenocene

2006 ◽  
Vol 25 (22) ◽  
pp. 5466-5476 ◽  
Author(s):  
Sergey A. Kuklin ◽  
Alexey M. Sheloumov ◽  
Fedor M. Dolgushin ◽  
Mariam G. Ezernitskaya ◽  
Alexander S. Peregudov ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Iridium Catalysts ◽  
Alkane Dehydrogenation ◽  
Highly Active

scholarly journals Rational Design and Synthesis of Right-Handed d-Sulfono-γ-AApeptide Helical Foldamers as Potent Inhibitors of Protein–Protein Interactions

2020 ◽  
Vol 85 (16) ◽  
pp. 10552-10560
Author(s):  
Peng Sang ◽  
Yan Shi ◽  
Pirada Higbee ◽  
Minghui Wang ◽  
Sami Abdulkadir ◽  
...  
Keyword(s):  
Protein Interactions ◽  
Rational Design ◽  
Protein Protein Interactions ◽  
Design And Synthesis

scholarly journals Facet-Dependent Reactivity of Ceria Nanoparticles Exemplified by CeO2-Based Transition Metal Catalysts: A Critical Review

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 452
Author(s):  
Michalis Konsolakis ◽  
Maria Lykaki
Keyword(s):  
Transition Metal ◽  
Co Oxidation ◽  
Critical Review ◽  
Rational Design ◽  
Metal Catalysts ◽  
Co2 Hydrogenation ◽  
Transition Metal Catalysts ◽  
Fine Tuning ◽  
Ceria Nanoparticles ◽  
Highly Active

The rational design and fabrication of highly-active and cost-efficient catalytic materials constitutes the main research pillar in catalysis field. In this context, the fine-tuning of size and shape at the nanometer scale can exert an intense impact not only on the inherent reactivity of catalyst’s counterparts but also on their interfacial interactions; it can also opening up new horizons for the development of highly active and robust materials. The present critical review, focusing mainly on our recent advances on the topic, aims to highlight the pivotal role of shape engineering in catalysis, exemplified by noble metal-free, CeO2-based transition metal catalysts (TMs/CeO2). The underlying mechanism of facet-dependent reactivity is initially discussed. The main implications of ceria nanoparticles’ shape engineering (rods, cubes, and polyhedra) in catalysis are next discussed, on the ground of some of the most pertinent heterogeneous reactions, such as CO2 hydrogenation, CO oxidation, and N2O decomposition. It is clearly revealed that shape functionalization can remarkably affect the intrinsic features and in turn the reactivity of ceria nanoparticles. More importantly, by combining ceria nanoparticles (CeO2 NPs) of specific architecture with various transition metals (e.g., Cu, Fe, Co, and Ni) remarkably active multifunctional composites can be obtained due mainly to the synergistic metalceria interactions. From the practical point of view, novel catalyst formulations with similar or even superior reactivity to that of noble metals can be obtained by co-adjusting the shape and composition of mixed oxides, such as Cu/ceria nanorods for CO oxidation and Ni/ceria nanorods for CO2 hydrogenation. The conclusions derived could provide the design principles of earth-abundant metal oxide catalysts for various real-life environmental and energy applications.

Rational design and synthesis of novel Syk-kinase inhibitors

2012 ◽  
Vol 22 (2) ◽  
pp. 73-74 ◽  
Author(s):  
Alexey A. Zeifman ◽  
Ilya Yu. Titov ◽  
Igor V. Svitanko ◽  
Tatiana V. Rakitina ◽  
Aleksey V. Lipkin ◽  
...  
Keyword(s):  
Rational Design ◽  
Kinase Inhibitors ◽  
Design And Synthesis ◽  
Syk Kinase

Rational design and synthesis of multimorphology mesoporous carbon@silica nanoparticles with tailored structure

Carbon ◽  
2021 ◽  
Author(s):  
Yajuan Zhao ◽  
Haolin Lyu ◽  
Yujie Liu ◽  
Wenjie Liu ◽  
Yong Tian ◽  
...  
Keyword(s):  
Silica Nanoparticles ◽  
Mesoporous Carbon ◽  
Rational Design ◽  
Design And Synthesis

Electrochemical oxidation of 5-hydroxymethylfurfural on ternary metal-organic frameworks nanoarrays: enhancement from electronic structure modulation

2021 ◽  
Author(s):  
Xiaojue Bai ◽  
Wenxiu He ◽  
Xingyu Lu ◽  
Yu Fu ◽  
Wei Qi
Keyword(s):  
Electronic Structure ◽  
Carboxylic Acid ◽  
Electrochemical Oxidation ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Highly Active ◽  
Ternary Metal ◽  
Metal Organic ◽  
Structure Modulation

The rational design and exploitation of highly active and stable catalysts for the electrochemical oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to valuable chemical 2,5-furandi-carboxylic acid (FDCA), is of great significance. Herein,...

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