Gas-Phase Study of Phenylacetylene and Norbornadiene on a Palladium(II) Phosphinous Acid Complex: Importance of the Order of Introduction of the Organic Partners

2009 ◽  
Vol 28 (9) ◽  
pp. 2735-2743 ◽  
Author(s):  
Reddy Thota ◽  
Denis Lesage ◽  
Yves Gimbert ◽  
Laurent Giordano ◽  
Stéphane Humbel ◽  
...  
Keyword(s):  
Gas Phase ◽  
Acid Complex ◽  
Phosphinous Acid ◽  
Phase Study

“Stripping” the Carbon Atom of Methyl Halide by a Cationic Holmium Complex: A Gas-Phase Study

2015 ◽  
Vol 21 (41) ◽  
pp. 14305-14308 ◽  
Author(s):  
Shaodong Zhou ◽  
Maria Schlangen ◽  
Jilai Li ◽  
Xiao-Nan Wu ◽  
Helmut Schwarz
Keyword(s):  
Carbon Atom ◽  
Gas Phase ◽  
Phase Study ◽  
Methyl Halide

Gas phase study of a 2-chloro-p-xylene discharge

2010 ◽  
Author(s):  
Isabel C Estrada-Raygoza ◽  
Gabriel Padron-Wells ◽  
Lawrence J. Overzet ◽  
Matthew J. Goeckner
Keyword(s):  
Gas Phase ◽  
Phase Study

scholarly journals Infrared gas phase study on plasma-polymer interactions in high-current diffuse dielectric barrier discharge

2017 ◽  
Vol 121 (24) ◽  
pp. 243301 ◽  
Author(s):  
Y. Liu ◽  
S. Welzel ◽  
S. A. Starostin ◽  
M. C. M. van de Sanden ◽  
R. Engeln ◽  
...  
Keyword(s):  
Gas Phase ◽  
Dielectric Barrier Discharge ◽  
Barrier Discharge ◽  
Plasma Polymer ◽  
High Current ◽  
Dielectric Barrier ◽  
Phase Study ◽  
Polymer Interactions

Thermochemistry of Elementary Actinide Sulfide Molecules: A Gas-Phase Study of Curium Sulfide

2010 ◽  
Vol 1264 ◽  
Author(s):  
Cláudia C. L. Pereira ◽  
Joaquim Marçalo ◽  
John K. Gibson
Keyword(s):  
Gas Phase ◽  
Bond Dissociation Energies ◽  
Gas Phase Reactions ◽  
General Applicability ◽  
Molecular Systems ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Phase Study ◽  
Fundamental Understanding ◽  
Actinide Ions

AbstractExperiments to explore the reactivity and thermochemistry of elementary transuranium sulfide molecules have been initiated to expand the basis for a fundamental understanding of actinide bonding, and to enable the development of advanced theoretical methodologies which will be of general applicability to more complex molecular systems. Bimolecular gas-phase reactions between transuranium actinide ions and neutral reagents are employed to obtain thermochemical information. The initial actinide sulfide studies have focused on obtaining the 298 K bond dissociation energy for the CmS+ ion, D[Cm+-S] = 475±37 kJ mol-1; from this result and an estimate of IE[CmS] ≈ IE[CmO] + 0.5 eV, we obtain D[Cm-S] = 563±64 kJ mol-1. The bond dissociation energies, D[Cm+-S] and D[Cm-S] are approximately 200 kJ mol-1 and 150 kJ mol-1 lower than for the corresponding oxides, CmO+ and CmO. The nature of the bonding in the CmS+ ion appears to be generally similar to that in other oxophilic metal sulfides. Comparisons with previous bond dissociation energies reported for ThS and US may suggest a difference in the An-S bonds for these early actinide sulfides as compared with CmS.

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