scholarly journals Carbon–Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule Cp*2Yb(4,7-Me2phen)

2014 ◽  
Vol 33 (23) ◽  
pp. 6819-6829 ◽  
Author(s):  
Grégory Nocton ◽  
Corwin H. Booth ◽  
Laurent Maron ◽  
Louis Ricard ◽  
Richard A. Andersen
Keyword(s):  
Hydrogen Bond ◽  
Open Shell ◽  
Bond Breaking

On the Hydrogen Bond Breaking Ability of Fluorocarbons Containing Higher Halogens

1974 ◽  
Vol 52 (21) ◽  
pp. 3612-3622 ◽  
Author(s):  
Thérèse Di Paolo ◽  
C. Sandorfy
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Bond Breaking ◽  
Anesthetic Activity ◽  
Competitive Mechanism ◽  
Infrared Measurements ◽  
Donor Acceptor

Infrared measurements show that fluorocarbons containing higher halogens are able to open O—H---O, N—H---N, S—H---S, N—H---O=C, type hydrogen bonds. This is probably due to a competitive mechanism of association consisting in the formation of donor–acceptor complexes. It is suggested that the breaking or perturbation of hydrogen bonds by this mechanism is of importance for the explanation of the anesthetic activity of these compounds.

Hydrogen bond breaking by oxygen and nitrogen

1983 ◽  
Vol 87 (22) ◽  
pp. 4355-4357 ◽  
Author(s):  
T. L. Mathers ◽  
G. Schoffler ◽  
S. P. McGlynn
Keyword(s):  
Hydrogen Bond ◽  
Bond Breaking

The effects of selected gases upon ethanol: hydrogen bond breaking by O2 and N2

1985 ◽  
Vol 63 (7) ◽  
pp. 1864-1869
Author(s):  
T. L. Mathers ◽  
G. Schoeffler ◽  
S. P. McGlynn
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Aromatic Hydrocarbons ◽  
Bonding Process ◽  
Bond Breaking ◽  
Temperature Dependency ◽  
Normal Hydrogen ◽  
Luminescence Characteristics

The temperature dependency of the phosphorescence properties of aromatic hydrocarbons in alcoholic glasses exhibits a number of phenomena that have not been described previously. Chief among these are the effects of added gases (O2, N2, C2H6, Ar), some of which produce major changes in the luminescence characteristics. These are discussed, and rationalized in terms of a model which presumes that O2 and N2 can disrupt the normal hydrogen bonding process between alcohol molecules.

Controlled Hydrogen-Bond Breaking in a Rotaxane by Discrete Solvation

2010 ◽  
Vol 122 (23) ◽  
pp. 3988-3992 ◽  
Author(s):  
Anouk M. Rijs ◽  
Nadja Sändig ◽  
Martine N. Blom ◽  
Jos Oomens ◽  
Jeffrey S. Hannam ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Breaking
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