scholarly journals Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site

2014 ◽  
Vol 33 (20) ◽  
pp. 5897-5906 ◽  
Author(s):  
James C. Lansing ◽  
James M. Camara ◽  
Danielle E. Gray ◽  
Thomas B. Rauchfuss
Keyword(s):  
Hydrogen Production ◽  
Active Site ◽  
Biomimetic Models

Selenium-bridged diiron hexacarbonyl complexes as biomimetic models for the active site of Fe–Fe hydrogenases

2008 ◽  
pp. 2128 ◽  
Author(s):  
Shang Gao ◽  
Jiangli Fan ◽  
Shiguo Sun ◽  
Xiaojun Peng ◽  
Xing Zhao ◽  
...  
Keyword(s):  
Active Site ◽  
Biomimetic Models

scholarly journals Active Site Elucidation and Optimization in Pt Co-catalysts for Photocatalytic Hydrogen Production over Titania

ChemCatChem ◽  
2017 ◽  
Vol 9 (22) ◽  
pp. 4268-4274 ◽  
Author(s):  
Zhi Jiang ◽  
Mark A. Isaacs ◽  
Zheng Wen Huang ◽  
Wenfeng Shangguan ◽  
Yifeng Deng ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Active Site ◽  
Photocatalytic Hydrogen Production ◽  
Co Catalysts

Hydrogen Production by the Naked Active Site of the Di-iron Hydrogenases in Water

2009 ◽  
Vol 113 (39) ◽  
pp. 13096-13106 ◽  
Author(s):  
Federico Zipoli ◽  
Roberto Car ◽  
Morrel H. Cohen ◽  
Annabella Selloni
Keyword(s):  
Hydrogen Production ◽  
Active Site

Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic

2012 ◽  
Vol 48 (79) ◽  
pp. 9816 ◽  
Author(s):  
Anindya Roy ◽  
Christopher Madden ◽  
Giovanna Ghirlanda
Keyword(s):  
Hydrogen Production ◽  
Active Site ◽  
Helical Peptide

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

2014 ◽  
Vol 47 (8) ◽  
pp. 2621-2630 ◽  
Author(s):  
Bojana Ginovska-Pangovska ◽  
Arnab Dutta ◽  
Matthew L. Reback ◽  
John C. Linehan ◽  
Wendy J. Shaw
Keyword(s):  
Hydrogen Production ◽  
Coordination Sphere ◽  
Active Site ◽  
Outer Coordination Sphere ◽  
The Impact

Synthesis of biomimetic models of iron-only hydrogenases active site linked to Ru-polypyridine photosensitizers

2003 ◽  
Vol 96 (1) ◽  
pp. 57
Author(s):  
Licheng Sun ◽  
Sascha Oft ◽  
Szabolcs Salyi ◽  
Henriette Wolpher ◽  
Mikael Kritikos ◽  
...  
Keyword(s):  
Active Site ◽  
Biomimetic Models

Structural basis of [NiFe] hydrogenase maturation by Hyp proteins

2012 ◽  
Vol 393 (10) ◽  
pp. 1089-1100 ◽  
Author(s):  
Satoshi Watanabe ◽  
Daisuke Sasaki ◽  
Taiga Tominaga ◽  
Kunio Miki
Keyword(s):  
Hydrogen Production ◽  
Dynamic Process ◽  
Active Site ◽  
The Other ◽  
Structural Basis ◽  
Structural Studies ◽  
Hydrogenase Maturation ◽  
Recent Advances

Abstract [NiFe] hydrogenases catalyze reversible hydrogen production/consumption. The active site of [NiFe] hydrogenases contains a complex NiFe(CN)2CO center, and the biosynthesis/maturation of these enzymes is a complex and dynamic process, primarily involving six Hyp proteins (HypABCDEF). HypA and HypB are involved in the Ni insertion, whereas the other four Hyp proteins (HypCDEF) are required for the biosynthesis, assembly and insertion of the Fe(CN)2CO group. Over the last decades, a large number of functional and structural studies on maturation proteins have been performed, revealing detailed functions of each Hyp protein and the framework of the maturation pathway. This article will focus on recent advances in structural studies of the Hyp proteins and on mechanistic insights into the [NiFe] hydrogenase maturation.

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