Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes

1983 ◽  
Vol 2 (11) ◽  
pp. 1694-1696 ◽  
Author(s):  
Kohei Tamao ◽  
Neyoshi Ishida ◽  
Tatsu Tanaka ◽  
Makoto Kumada
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Synthesis ◽  
Peroxide Oxidation ◽  
Carbon Bond ◽  
Silicon Carbon ◽  
Hydrogen Peroxide Oxidation

Crystal and solution structure of (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile

1989 ◽  
Vol 54 (12) ◽  
pp. 3253-3259
Author(s):  
Jaroslav Podlaha ◽  
Miloš Buděšínský ◽  
Jana Podlahová ◽  
Jindřich Hašek
Keyword(s):  
Hydrogen Peroxide ◽  
Solution Structure ◽  
Peroxide Oxidation ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Study ◽  
Hydrogen Peroxide Oxidation ◽  
Unusual Product ◽  
C Nmr

The unusual product of the reaction of 2-chloroacrylonitrile with ethane thiol and following hydrogen peroxide oxidation was found to be (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile by means of X-ray crystallography. 1H and 13C NMR study of this compound has proven the same conformation of the molecule in solution.

scholarly journals Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen2NH3NCS]2+: The Preparation and Properties of trans-[Coen2NH3CN]2+

1973 ◽  
Vol 51 (24) ◽  
pp. 4152-4158 ◽  
Author(s):  
Albert Richard Norris ◽  
James William Lennox Wilson
Keyword(s):  
Hydrogen Peroxide ◽  
Spectral Properties ◽  
Peroxide Oxidation ◽  
Reaction Conditions ◽  
Thiocyanate Ion ◽  
Hydrogen Peroxide Oxidation ◽  
Percent Conversion ◽  
Cis And Trans ◽  
In Cis

The hydrogen peroxide oxidation of thiocyanate ion in cis- and trans-[Coen2NH3NCS]2+ leads to the formation of the corresponding cis- and trans-cyanoammine- and diamminebis(ethylenediamine)cobalt-(III) complexes. The spectral properties of the previously unreported trans-[Coe2NH3CN]2+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trans-[Coen2NH3NCS]2+ to trans-[Coen2NH3CN]2+.

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