Theoretical Studies on a New Class of C–C Bond Formation: Palladium-Catalyzed Reactions of α-Diazocarbonyl Compounds with Allylic Esters

2014 ◽  
Vol 33 (6) ◽  
pp. 1404-1415 ◽  
Author(s):  
Hongliang Wang ◽  
Xu Yang ◽  
Yuxia Liu ◽  
Siwei Bi
Keyword(s):  
Bond Formation ◽  
Theoretical Studies ◽  
New Class ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions ◽  
Allylic Esters

scholarly journals New trends in the cross-coupling and other catalytic reactions

2017 ◽  
Vol 89 (10) ◽  
pp. 1413-1428 ◽  
Author(s):  
Irina P. Beletskaya ◽  
Alexei D. Averin
Keyword(s):  
Lewis Acids ◽  
Bond Formation ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Catalytic Reactions ◽  
Coupling Reactions ◽  
Ch Activation ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions

AbstractA mini-review covers the latest achievements in the field of metal-mediated cross-coupling reactions among which are palladium-catalyzed Heck, Suzuki, cyanation and amination reactions. The aspects of the application of Pd nanoparticles (PdNPs) are discussed. The possibilities of the applications of Cu(I)-catalyzed reactions are described. Special emphasis is made on the synthesis of polymacrocyclic compounds like porphyrin dyads and triads, polyazacryptands bearing fluorophore groups using catalytic methods. The application of Pd-catalyzed CH-activation reactions for porphyrin modifications is described, the use of Lewis acids catalysis and organocatalysis for enantioselective C–C bond formation is considered with the emphasis on the application of immobilized organocatalyst.

Palladium-catalyzed cascade cyclizations involving C–C and C–X bond formation: strategic applications in natural product synthesis

2021 ◽  
Author(s):  
K. R. Holman ◽  
A. M. Stanko ◽  
S. E. Reisman
Keyword(s):  
Natural Product ◽  
Bond Formation ◽  
Natural Product Synthesis ◽  
Cascade Cyclizations ◽  
Palladium Catalyzed ◽  
Multiple Rings

This tutorial review highlights the use of palladium-catalyzed cascade cyclizations in natural product synthesis, focusing on cascades that construct multiple rings and form both C–C and C–X (X = O, N) bonds in a single synthetic operation.

Sign in / Sign up

Export Citation Format

Share Document