Phosphine-Substituted (η5-Pentadienyl) Manganese Carbonyl Complexes: Geometric Structures, Electronic Structures, and Energetic Properties of the Associative Substitution Mechanism, Including Isolation of the Slipped η3-Pentadienyl Associative Intermediate

2013 ◽  
Vol 33 (1) ◽  
pp. 278-288 ◽  
Author(s):  
José Ignacio de la Cruz Cruz ◽  
Patricia Juárez-Saavedra ◽  
Brenda Paz-Michel ◽  
Marco Antonio Leyva-Ramirez ◽  
Asha Rajapakshe ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Carbonyl Complexes ◽  
Geometric Structures ◽  
Energetic Properties ◽  
Substitution Mechanism ◽  
Manganese Carbonyl

Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]

2008 ◽  
Vol 27 (13) ◽  
pp. 3272-3278 ◽  
Author(s):  
Theresa I. Kückmann ◽  
Frauke Schödel ◽  
Inge Sänger ◽  
Michael Bolte ◽  
Matthias Wagner ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Carbonyl Complexes ◽  
Thiolate Ligands ◽  
Manganese Carbonyl

Coupling of iminoacyl groups to diazabutadienes on manganese carbonyl complexes

1989 ◽  
Vol 8 (6) ◽  
pp. 1523-1533 ◽  
Author(s):  
Philip L. Motz ◽  
John P. Williams ◽  
John J. Alexander ◽  
Douglas M. Ho ◽  
John S. Ricci ◽  
...  
Keyword(s):  
Carbonyl Complexes ◽  
Manganese Carbonyl

13C,17O and55Mn NMR studies on substituted manganese carbonyl complexes. A contribution to the mechanism of demetalation reactions

1998 ◽  
Vol 36 (S1) ◽  
pp. S54-S60 ◽  
Author(s):  
Daniel Rentsch ◽  
Lilan Nill ◽  
Wolfgang von Philipsborn ◽  
D. Richard Sidler ◽  
Philip J. Rybczynski ◽  
...  
Keyword(s):  
Carbonyl Complexes ◽  
Nmr Studies ◽  
Manganese Carbonyl

ChemInform Abstract: Reactions of an Imidoyl Halide with Manganese Carbonyl Complexes.

ChemInform ◽  
1990 ◽  
Vol 21 (11) ◽  
Author(s):  
P. L. MOTZ ◽  
J. J. ALEXANDER ◽  
C. F. CAMPANA
Keyword(s):  
Carbonyl Complexes ◽  
Manganese Carbonyl

Ligand effects on CO bridging in binuclear manganese carbonyl complexes

1982 ◽  
Vol 1 (12) ◽  
pp. 1667-1670 ◽  
Author(s):  
Thomas E. Wolff ◽  
Lawrence P. Klemann
Keyword(s):  
Carbonyl Complexes ◽  
Ligand Effects ◽  
Manganese Carbonyl

Synthesis and characterization of heteroscorpionate-based manganese carbonyl complexes as CO-releasing molecules

Tetrahedron ◽  
2015 ◽  
Vol 71 (19) ◽  
pp. 2951-2954 ◽  
Author(s):  
Frank Strinitz ◽  
Philipp Trautner ◽  
Hendrik Pfeiffer ◽  
Ulrich Schatzschneider ◽  
Nicolai Burzlaff
Keyword(s):  
Synthesis And Characterization ◽  
Carbonyl Complexes ◽  
Manganese Carbonyl

Theoreticalversusexperimental geometries in S-bridged manganese carbonyl complexes

2003 ◽  
Vol 36 (4) ◽  
pp. 1050-1055 ◽  
Author(s):  
Juan F. Van der Maelen Uría ◽  
Javier Ruiz ◽  
Santiago García-Granda
Keyword(s):  
Density Functional ◽  
Theoretical Calculations ◽  
Basis Sets ◽  
Medium Size ◽  
Carbonyl Complexes ◽  
X Ray Diffraction ◽  
Bond Lengths ◽  
Hartree Fock ◽  
Experimental Geometry ◽  
Manganese Carbonyl

The experimental geometry obtained from single-crystal X-ray diffraction for a number of binuclear S-bridged manganese complexes is compared with the results of theoretical calculations made at theab initiolevel by using Hartree–Fock and density functional theory methods with medium-size and large basis sets. The optimized geometries obtained were somewhat relaxed when compared with the experimental ones, with very similar bond and torsion angles but longer bond lengths. The mean square deviation for bond lengths (angles) was found to be between 0.046 Å (1.1°) and 0.004 Å (0.7°) depending on the theoretical model used.

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