Unsymmetrically Substituted 1,1′-Biferrocenylenes Maintain Class III Mixed-Valence Character

2013 ◽  
Vol 32 (20) ◽  
pp. 5980-5987 ◽  
Author(s):  
Rochus Breuer ◽  
Michael Schmittel
Keyword(s):  
Mixed Valence ◽  
Class Iii

Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

2013 ◽  
Vol 126 (5) ◽  
pp. 1317-1320 ◽  
Author(s):  
German E. Pieslinger ◽  
Pablo Alborés ◽  
Leonardo D. Slep ◽  
Luis M. Baraldo
Keyword(s):  
Mixed Valence ◽  
Class Iii ◽  
Mixed Valence Complex

scholarly journals Vibrational Coherence Due to Promoting Mode Activity in the Relaxation Dynamics of the Class III Mixed-Valence Molecule [Ru2TIEDCl4]+

2002 ◽  
Vol 106 (7) ◽  
pp. 1131-1143 ◽  
Author(s):  
Timothy W. Marin ◽  
Bradley J. Homoelle ◽  
Kenneth G. Spears ◽  
Joseph T. Hupp ◽  
Larry O. Spreer
Keyword(s):  
Mixed Valence ◽  
Relaxation Dynamics ◽  
Class Iii ◽  
Vibrational Coherence

Correction to From Molecular Wires to Molecular Resistors: TCNE, a Class-III/Class-II Mixed-Valence Chemical Switch

2014 ◽  
Vol 33 (19) ◽  
pp. 5618-5618 ◽  
Author(s):  
Alexandre Burgun ◽  
Benjamin G. Ellis ◽  
Thierry Roisnel ◽  
Brian W. Skelton ◽  
Michael I. Bruce ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Molecular Wires ◽  
Class Ii ◽  
Class Iii

Class III mixed-valence: A copper—copper bond?

1991 ◽  
Vol 43 (2-3) ◽  
pp. 221
Author(s):  
Charlie Harding ◽  
Vickie McKee ◽  
Jane Nelson
Keyword(s):  
Mixed Valence ◽  
Class Iii

Distinguishing the Strength of Electronic Coupling for Mo2-Containing Mixed-Valence Compounds within the Class III Regime

2014 ◽  
Vol 21 (6) ◽  
pp. 2353-2357 ◽  
Author(s):  
Tao Cheng ◽  
Ying Ning Tan ◽  
Yu Zhang ◽  
Yu Yu Zhang ◽  
Miao Meng ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Electronic Coupling ◽  
Class Iii ◽  
Mixed Valence Compounds

Infrared Study of the Class II/Class III Boundary in Mixed-Valence Dinuclear Ruthenium Complexes

2001 ◽  
Vol 123 (7) ◽  
pp. 1396-1402 ◽  
Author(s):  
Maria C. DeRosa ◽  
Christopher A. White ◽  
Christopher E. B. Evans ◽  
Robert J. Crutchley
Keyword(s):  
Mixed Valence ◽  
Ruthenium Complexes ◽  
Class Ii ◽  
Class Iii ◽  
Infrared Study ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Pseudo-para-dinitro[2.2]paracyclophane Radical Anion, a Mixed-Valence System Poised on the Class II/Class III Borderline

2005 ◽  
Vol 127 (3) ◽  
pp. 920-925 ◽  
Author(s):  
Stephen F. Nelsen ◽  
Asgeir E. Konradsson ◽  
João P. Telo
Keyword(s):  
Radical Anion ◽  
Mixed Valence ◽  
Class Ii ◽  
Class Iii

A study of asymmetrical mixed-valent Mo2–Mo2 complexes in the class III regime

2017 ◽  
Vol 46 (17) ◽  
pp. 5711-5723 ◽  
Author(s):  
Suman Mallick ◽  
Tao Cheng ◽  
Lu Chen ◽  
Miao Meng ◽  
Yu Yu Zhang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Dft Calculations ◽  
Mixed Valence ◽  
Class Iii ◽  
Bridging Ligands ◽  
Strongly Coupled

With thiolated oxalato bridging ligands, three strongly coupled, asymmetrical Mo2 dimers have been studied. In these strongly mixed-valence systems, the charge is unevenly distributed and electron transfer between the two bridged Mo2 centers occurs, as indicated by the LMCT absorption and supported by the DFT calculations.

scholarly journals Triazatruxene radical cation: a trigonal class III mixed valence system

RSC Advances ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 821-825 ◽  
Author(s):  
Tony George Thomas ◽  
Sarap Chandra Shekar ◽  
Rotti Srinivasamurthy Swathi ◽  
Karical Raman Gopidas
Keyword(s):  
Radical Cation ◽  
Mixed Valence ◽  
Class Iii ◽  
System P ◽  
First Time

The highly symmetric and stable triazatruxene radical cation was generated chemically for the first time.

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