Cationic Iridium Complexes Containing Anionic Iridium Counterions Supported by Redox-Active N-Heterocyclic Carbenes

2013 ◽  
Vol 32 (15) ◽  
pp. 4334-4341 ◽  
Author(s):  
Kuppuswamy Arumugam ◽  
Jinho Chang ◽  
Vincent M. Lynch ◽  
Christopher W. Bielawski
Keyword(s):  
Heterocyclic Carbenes ◽  
Iridium Complexes ◽  
Redox Active

Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine

2008 ◽  
Vol 27 (8) ◽  
pp. 1936-1943 ◽  
Author(s):  
Guoyong Song ◽  
Yao Zhang ◽  
Xingwei Li
Keyword(s):  
Heterocyclic Carbenes ◽  
Iridium Complexes

Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation:  Structure and Dynamics

2003 ◽  
Vol 22 (8) ◽  
pp. 1663-1667 ◽  
Author(s):  
Anthony R. Chianese ◽  
Xingwei Li ◽  
Michael C. Janzen ◽  
J. W. Faller ◽  
Robert H. Crabtree
Keyword(s):  
Heterocyclic Carbenes ◽  
Iridium Complexes ◽  
Structure And Dynamics

A coordinatively unsaturated iridium complex with an unsymmetrical redox-active ligand: (spectro)electrochemical and reactivity studies

2019 ◽  
Vol 48 (37) ◽  
pp. 13931-13942 ◽  
Author(s):  
Sebastian Sobottka ◽  
Margarethe Behr van der Meer ◽  
Estelle Glais ◽  
Uta Albold ◽  
Simon Suhr ◽  
...  
Keyword(s):  
Bond Activation ◽  
Iridium Complex ◽  
Iridium Complexes ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Metal Ligand

Metal–ligand cooperativity can be used in iridium complexes with an unsymmetrically substituted redox-active diamidobenzene ligand for bond activation reactions.

Oxidation of Dihydrogen by Iridium Complexes of Redox-Active Ligands

2010 ◽  
Vol 29 (8) ◽  
pp. 1956-1965 ◽  
Author(s):  
Mark R. Ringenberg ◽  
Mark J. Nilges ◽  
Thomas B. Rauchfuss ◽  
Scott R. Wilson
Keyword(s):  
Iridium Complexes ◽  
Redox Active Ligands ◽  
Redox Active

scholarly journals Copper catalysis with redox-active ligands

2020 ◽  
Vol 16 ◽  
pp. 858-870 ◽  
Author(s):  
Agnideep Das ◽  
Yufeng Ren ◽  
Cheriehan Hessin ◽  
Marine Desage-El Murr
Keyword(s):  
Electron Transfer ◽  
Coordination Sphere ◽  
Copper Complexes ◽  
Heterocyclic Carbenes ◽  
Metal Center ◽  
Copper Catalysis ◽  
Redox Active Ligands ◽  
Elementary Steps ◽  
Cooperative Catalysis ◽  
Redox Active

Copper catalysis finds applications in various synthetic fields by utilizing the ability of copper to sustain mono- and bielectronic elementary steps. Further to the development of well-defined copper complexes with classical ligands such as phosphines and N-heterocyclic carbenes, a new and fast-expanding area of research is exploring the possibility of a complementing metal-centered reactivity with electronic participation by the coordination sphere. To achieve this electronic flexibility, redox-active ligands can be used to engage in a fruitful “electronic dialogue” with the metal center, and provide additional venues for electron transfer. This review aims to present the latest results in the area of copper-based cooperative catalysis with redox-active ligands.

Rhodium and iridium complexes of N-heterocyclic carbenes: Structural investigations and their catalytic properties in the borylation reaction

2006 ◽  
Vol 691 (26) ◽  
pp. 5725-5738 ◽  
Author(s):  
Guido D. Frey ◽  
Christoph F. Rentzsch ◽  
Denise von Preysing ◽  
Tobias Scherg ◽  
Michael Mühlhofer ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Heterocyclic Carbenes ◽  
Iridium Complexes ◽  
Structural Investigations
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