Monophosphine-o-Carborane Sulfide as a Noninnocent Ligand for C,S, S,S′, and B,S,S′ Coordination Modes of Half-Sandwich Iridium and Rhodium Complexes

2011 ◽  
Vol 30 (20) ◽  
pp. 5365-5373 ◽  
Author(s):  
Zi-Jian Yao ◽  
Guo-Xin Jin
Keyword(s):  
Rhodium Complexes ◽  
Coordination Modes ◽  
Half Sandwich

scholarly journals Half-sandwich complexes of rhodium containing cysteine-derived ligands

2016 ◽  
Vol 45 (36) ◽  
pp. 14203-14215 ◽  
Author(s):  
María Carmona ◽  
Ricardo Rodríguez ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Iñaki Osante ◽  
...  
Keyword(s):  
Absolute Configuration ◽  
Crystallographic Data ◽  
Rhodium Complexes ◽  
Sandwich Complexes ◽  
Coordination Modes ◽  
The Absolute ◽  
Half Sandwich

Five distinct coordination modes have been disclosed for rhodium complexes containing modified cysteines. From the spectroscopic, theoretical and crystallographic data, the absolute configuration of the compounds has been established.

Structural and chemical properties of half-sandwich rhodium complexes supported by the bis(2-pyridyl)methane ligand

2019 ◽  
Vol 48 (33) ◽  
pp. 12396-12406 ◽  
Author(s):  
Davide Lionetti ◽  
Victor W. Day ◽  
James D. Blakemore
Keyword(s):  
Chemical Properties ◽  
Oxidation States ◽  
Rhodium Complexes ◽  
Half Sandwich ◽  
And Chemical Properties

The bis(2-pyridyl)methane ligand can support [Cp*Rh] complexes (Cp* = pentamethylcyclopentadienyl) in the Rh(iii) and Rh(ii) oxidation states. Structural and reactivity studies demonstrate significant differences between these complexes and notable analogues bearing the related dimethylbis(2-pyridyl)methane ligand.

Mechanistic insights and computational design of half-sandwich iridium and rhodium complexes for hydrogenation of quinoline

2019 ◽  
Vol 43 (22) ◽  
pp. 8459-8464
Author(s):  
Xiuli Yan ◽  
Xinzheng Yang
Keyword(s):  
Dft Calculations ◽  
Hydride Transfer ◽  
Computational Design ◽  
Transfer Mechanism ◽  
Rhodium Complexes ◽  
Half Sandwich

DFT calculations reveal a stepwise proton and hydride transfer mechanism for the hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline catalysed by half-sandwich Cp*Ir(NHC) complexes.

scholarly journals Strong metal–borane interactions in low-valent cyclopentadienyl rhodium complexes

2019 ◽  
Vol 55 (85) ◽  
pp. 12837-12840
Author(s):  
Maxime Boudjelel ◽  
Sonia Mallet-Ladeira ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Rhodium Complexes ◽  
Low Valent ◽  
Half Sandwich

Half-sandwich Rh(i) complexes stabilized by η3-BCC or η1-B borane coordination.

scholarly journals Half-sandwich complexes of iridium and ruthenium containing cysteine-derived ligands

2017 ◽  
Vol 46 (3) ◽  
pp. 962-976 ◽  
Author(s):  
María Carmona ◽  
Ricardo Rodríguez ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Carlos Cativiela ◽  
...  
Keyword(s):  
Absolute Configuration ◽  
Crystallographic Data ◽  
Sandwich Complexes ◽  
Coordination Modes ◽  
Chiral Compounds ◽  
The Absolute ◽  
Half Sandwich

Modified cysteines display five distinct coordination modes towards (C5Me5)Ir and (η6-p-MeC6H4iPr)Ru moieties. From spectroscopic and crystallographic data, the absolute configuration of the resulting chiral compounds has been established.

scholarly journals Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction

2013 ◽  
Vol 33 (1) ◽  
pp. 45-52 ◽  
Author(s):  
Barbara Procacci ◽  
Robin J. Blagg ◽  
Robin N. Perutz ◽  
Nuria Rendón ◽  
Adrian C. Whitwood
Keyword(s):  
Photochemical Reactions ◽  
Rhodium Complexes ◽  
Half Sandwich ◽  
Competing Pathways
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