Preparation of Incomplete Cubane-Type Ru2M(μ3-S)(μ2-Cl)3Clusters (M = Sb, Bi) and Isolation of the Ru2Sb Cluster Having a Novel μ3-SO Ligand. Functions in Oxygen Atom Transfer and Catalytic Oxidation of PPh3to O═PPh3by Molecular O2

2011 ◽  
Vol 30 (11) ◽  
pp. 2939-2946 ◽  
Author(s):  
Kazumasa Oya ◽  
Hidetake Seino ◽  
Midori Akiizumi ◽  
Yasushi Mizobe
Keyword(s):  
Oxygen Atom ◽  
Catalytic Oxidation ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

scholarly journals Activation of molecular oxygen by a molybdenum complex for catalytic oxidation

2015 ◽  
Vol 44 (47) ◽  
pp. 20514-20522 ◽  
Author(s):  
Antoine Dupé ◽  
Martina E. Judmaier ◽  
Ferdinand Belaj ◽  
Klaus Zangger ◽  
Nadia C. Mösch-Zanetti
Keyword(s):  
Oxygen Atom ◽  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Atom Transfer ◽  
Peroxo Complex ◽  
Molybdenum Complex ◽  
Oxygen Atom Transfer ◽  
Oxygen Atoms

Activation of molecular oxygen by a Mo(iv) complex yields the corresponding oxo–peroxo complex, which is able to catalyze oxygen atom transfer to a model substrate by transferring both oxygen atoms of the peroxo group.

scholarly journals Oxygen Atom Transfer Catalysis by Dioxidomolybdenum(VI) Complexes of Pyridyl Aminophenolate Ligands

Polyhedron ◽  
2021 ◽  
pp. 115234
Author(s):  
Md. Kamal Hossain ◽  
Jörg A. Schachner ◽  
Matti Haukka ◽  
Michael G. Richmond ◽  
Nadia C. Mösch-Zanetti ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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