Salt Metathesis and Direct Reduction Reactions Leading to Group 3 Metal Complexes with aN,N′-Bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene Ligand and Their Solid-State Structures

2010 ◽  
Vol 29 (11) ◽  
pp. 2610-2615 ◽  
Author(s):  
Tarun K. Panda ◽  
Hiroshi Kaneko ◽  
Kuntal Pal ◽  
Hayato Tsurugi ◽  
Kazushi Mashima
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Direct Reduction ◽  
Reduction Reactions ◽  
Group 3 ◽  
Solid State Structures

scholarly journals Group 13 metal complexes containing the bis-(4-methylbenzoxazol-2-yl)-methanide ligand

2016 ◽  
Vol 45 (14) ◽  
pp. 6149-6158 ◽  
Author(s):  
David-R. Dauer ◽  
Melchior Flügge ◽  
Regine Herbst-Irmer ◽  
Dietmar Stalke
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Detailed Comparison ◽  
Group 13 ◽  
Solid State Structures

On the basis of the deprotonated bis-(4-methylbenzoxazol-2-yl)-methane ligand 1 a series of group 13 metal complexes was synthesised and fully characterised. A detailed comparison of solid state structures demonstrates clearly the similarity of methanide and the omnipresent nacnac ligand.

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

Synthesis and solid state structures of macromolecular cylindrical brushes with varying side chain length

Polymer ◽  
2004 ◽  
Vol 45 (12) ◽  
pp. 4009-4015 ◽  
Author(s):  
Bin Zhang ◽  
Shanju Zhang ◽  
Lidia Okrasa ◽  
Tadeusz Pakula ◽  
Tim Stephan ◽  
...  
Keyword(s):  
Solid State ◽  
Chain Length ◽  
Side Chain ◽  
Side Chain Length ◽  
Solid State Structures
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