Synthesis and Characterization of Tungsten(VI) Alkylidene Complexes Supported by an [OCO]3−Trianionic Pincer Ligand: Progress towards the [tBuOCO]W≡CC(CH3)3Fragment

2010 ◽  
Vol 29 (19) ◽  
pp. 4227-4233 ◽  
Author(s):  
Subramaniam Kuppuswamy ◽  
Andrew J. Peloquin ◽  
Ion Ghiviriga ◽  
Khalil A. Abboud ◽  
Adam S. Veige
Keyword(s):  
Synthesis And Characterization ◽  
Pincer Ligand ◽  
Alkylidene Complexes

A new ONO3− trianionic pincer ligand with intermediate flexibility and its tungsten alkylidene and alkylidyne complexes

2015 ◽  
Vol 44 (42) ◽  
pp. 18475-18486 ◽  
Author(s):  
Sudarsan VenkatRamani ◽  
Ion Ghiviriga ◽  
Khalil A. Abboud ◽  
Adam S. Veige
Keyword(s):  
Synthesis And Characterization ◽  
Pincer Ligand ◽  
Tungsten Alkylidene

This report details the synthesis and characterization of the semi-flexible [ONCH2O]H3 (1) ligand and its W(vi)-alkylidene and alkylidyne complexes.

scholarly journals Tuning the Bonding of a μ-Mesityl Ligand on Dicopper(I) through a Proton-Responsive Expanded PNNP Pincer Ligand

2019 ◽  
Author(s):  
Errikos Kounalis ◽  
Martin Lutz ◽  
Daniël Broere
Keyword(s):  
Electronic Structure ◽  
Dft Calculations ◽  
Crystal Packing ◽  
Nbo Analysis ◽  
Synthesis And Characterization ◽  
Protonation State ◽  
Pincer Ligand ◽  
Crystal Packing Effects ◽  
Packing Effects

<p>We report the synthesis and characterization of a series of cationic, neutral and anionic dicopper(I) complexes featuring a <i>µ</i>-mesityl ligand and a naphthyridine-derived PNNP expanded pincer ligand. Structural characterization showed that the protonation state of the dinucleating ligand has a pronounced effect on the bending and tilting of the <i>µ</i>-mesityl ligand. DFT calculations indicate that the varying orientations of the <i>µ</i>-mesityl ligand are inherent due to changes in electronic structure rather than crystal packing effects. NBO analysis reveals how the interactions that contribute to the 3-center 2-electron bond between the <i>µ</i>-mesityl ligand and the dicopper core change for the various degrees of observed bending and tilting. </p>

Synthesis and characterization of rhodium, iridium, and palladium complexes of a diarylamido-based PNSb pincer ligand

2018 ◽  
Vol 47 (33) ◽  
pp. 11619-11624 ◽  
Author(s):  
Alex J. Kosanovich ◽  
Aldo M. Jordan ◽  
Nattamai Bhuvanesh ◽  
Oleg. V. Ozerov
Keyword(s):  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Pincer Ligand

A new diarylmido-based pincer proto ligand (iPrPNHSbPh) with one –PPri2 and one –SbPh2 side donor has been synthesized.

scholarly journals Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand

RSC Advances ◽  
2018 ◽  
Vol 8 (25) ◽  
pp. 14092-14099 ◽  
Author(s):  
Peng Zhang ◽  
Xiaoyan Li ◽  
Xinghao Qi ◽  
Hongjian Sun ◽  
Olaf Fuhr ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Iron Complexes ◽  
Transfer Hydrogenation ◽  
Synthesis And Characterization ◽  
Pincer Ligand ◽  
Mild Conditions

The synthesis and characterization of a series of silyl hydrido iron complexes bearing a [PSiP] pincer ligand were reported. These complexes showed good to excellent catalytic activity for transfer hydrogenation of aldehydes under mild conditions.

Synthesis and Characterization of Silica-Stabilized Chromium(IV) Alkylidene Complexes

1998 ◽  
Vol 120 (2) ◽  
pp. 415-416 ◽  
Author(s):  
Jamila Amor Nait Ajjou ◽  
Susannah L. Scott ◽  
Valérie Paquet
Keyword(s):  
Synthesis And Characterization ◽  
Alkylidene Complexes

Synthesis and Characterization of a N,C,N-Carbodiphosphorane Pincer Ligand and Its Complexes

2019 ◽  
Vol 38 (19) ◽  
pp. 3768-3777 ◽  
Author(s):  
Marius Klein ◽  
Xiulan Xie ◽  
Olaf Burghaus ◽  
Jörg Sundermeyer
Keyword(s):  
Synthesis And Characterization ◽  
Pincer Ligand
Sign in / Sign up

Export Citation Format

Share Document