scholarly journals Intermolecular Dehydrative Coupling Reaction of Aryl Ketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium−Hydride Complex: A Novel Ketone Olefination Method via Vinyl C−H Bond Activation

2010 ◽  
Vol 29 (8) ◽  
pp. 1883-1885 ◽  
Author(s):  
Chae S. Yi ◽  
Do W. Lee
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Ruthenium Hydride ◽  
Hydride Complex ◽  
Aryl Ketones ◽  
Cyclic Alkenes

C−H Bond Activation by a Hydrotris(pyrazolyl)borato Ruthenium Hydride Complex

2003 ◽  
Vol 22 (4) ◽  
pp. 641-651 ◽  
Author(s):  
Siu Man Ng ◽  
Wai Han Lam ◽  
Chi Chuen Mak ◽  
Chun Wai Tsang ◽  
Guochen Jia ◽  
...  
Keyword(s):  
Bond Activation ◽  
Ruthenium Hydride ◽  
Hydride Complex

scholarly journals Synthesis of N-alkoxyphthalimide derivatives via PIDA-promoted cross dehydrogenative coupling reaction

RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 8051-8054
Author(s):  
Rongxiang Chen ◽  
Bing Liu ◽  
Wenbo Li ◽  
Kai-Kai Wang ◽  
Changqing Miao ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Dehydrogenative Coupling ◽  
Aryl Ketones ◽  
High Yields

A cross dehydrogenative coupling reaction of aryl ketones with N-hydroxyphthalimide was realized. The reactions afforded a clean and facile access to diverse N-alkoxyphthalimide derivatives in high yields (up to 99%).

ChemInform Abstract: Direct Dehydroxylative Coupling Reaction of Alcohols with Organosilanes Through Si-X Bond Activation by Halogen Bonding.

ChemInform ◽  
2015 ◽  
Vol 46 (44) ◽  
pp. no-no
Author(s):  
Masato Saito ◽  
Nobuya Tsuji ◽  
Yusuke Kobayashi ◽  
Yoshiji Takemoto
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Halogen Bonding

Palladium(0)-catalyzed cyclopropanation of benzyl bromides via C(sp3)–H bond activation

2014 ◽  
Vol 50 (28) ◽  
pp. 3692-3694 ◽  
Author(s):  
Jiangang Mao ◽  
Shuo-Qing Zhang ◽  
Bing-Feng Shi ◽  
Weiliang Bao
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Type Coupling

A novel Pd(0)-catalyzed domino cyclopropanation reaction was established. The process involves a Heck-type coupling reaction and a C(sp3)–H activation.

Arene C–H bond activation and methane formation by a methylplatinum(ii) complex: experimental and theoretical elucidation of the mechanism

2019 ◽  
Vol 43 (21) ◽  
pp. 8005-8014 ◽  
Author(s):  
Asma Nahaei ◽  
S. Masoud Nabavizadeh ◽  
Fatemeh Niroomand Hosseini ◽  
S. Jafar Hoseini ◽  
Mahdi M. Abu-Omar
Keyword(s):  
Bond Activation ◽  
Oxidative Addition ◽  
Methane Formation ◽  
Donor Atom ◽  
Computational Investigation ◽  
Hydride Complex

A combined experimental/computational investigation reveals that the cyclometalation of [PtMe2(DMSO)2], 1, by HC^N ligands proceeds via HC^N coordination through the N donor atom, oxidative addition of the arene C–H bond, and final dissociation of methane from a platinum hydride complex.

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