Palladium-Complex-Promoted Living Polymerization of 2-Alkoxy-1-methylenecyclopropanes. Synthesis of Linear and Cyclic Polymers and Block Copolymers Having Alkoxy and Vinylidene Groups

2006 ◽  
Vol 25 (17) ◽  
pp. 4062-4064 ◽  
Author(s):  
Daisuke Takeuchi ◽  
Akihisa Inoue ◽  
Kohtaro Osakada ◽  
Minoru Kobayashi ◽  
Kentaro Yamaguchi
Keyword(s):  
Block Copolymers ◽  
Palladium Complex ◽  
Living Polymerization ◽  
Cyclic Polymers

Regioselective living polymerization of allylcyclohexane and precise synthesis of hydrocarbon block copolymers with cyclic units

2018 ◽  
Vol 9 (9) ◽  
pp. 1109-1115 ◽  
Author(s):  
Jie Gao ◽  
Zonghang Ying ◽  
Liu Zhong ◽  
Heng Liao ◽  
Haiyang Gao ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Nickel Catalyst ◽  
Living Polymerization ◽  
Sequential Monomer Addition

Regioselective living polymerization of allylcyclohexane was catalyzed by a bulky α-diimine nickel catalyst. Well-defined hydrocarbon block copolymers with cyclic units were constructed by sequential monomer addition.

Supramolecular Block Copolymers by Seeded Living Polymerization of Perylene Bisimides

2019 ◽  
Vol 141 (30) ◽  
pp. 12044-12054 ◽  
Author(s):  
Wolfgang Wagner ◽  
Marius Wehner ◽  
Vladimir Stepanenko ◽  
Frank Würthner
Keyword(s):  
Block Copolymers ◽  
Living Polymerization ◽  
Perylene Bisimides

Recent Advances in Thermoplastic Elastomer Synthesis

1991 ◽  
Vol 64 (3) ◽  
pp. 450-468 ◽  
Author(s):  
Roderic P. Quirk ◽  
Jungahn Kim
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Structural Control ◽  
Thermoplastic Elastomer ◽  
Living Polymerization ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Recent Advances ◽  
Living Polymerizations

Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful extensions of this methodology to a wider variety of monomers.

Iterative Convergent Synthesis of Large Cyclic Polymers and Block Copolymers with Discrete Molecular Weights

2020 ◽  
Vol 142 (33) ◽  
pp. 14028-14032
Author(s):  
Mo Beom Koo ◽  
Seul Woo Lee ◽  
Jung Min Lee ◽  
Kyoung Taek Kim
Keyword(s):  
Block Copolymers ◽  
Cyclic Polymers ◽  
Convergent Synthesis ◽  
Molecular Weights
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