Reversible Intramolecular Alkyl C−H Bond Activation, Alcohol Dehydrogenation, and Trans−Cis Dihydride Isomerization in Ruthenium N-Heterocyclic Carbene Complexes

2004 ◽  
Vol 23 (20) ◽  
pp. 4537-4539 ◽  
Author(s):  
Suzanne Burling ◽  
Mary F. Mahon ◽  
Belinda M. Paine ◽  
Michael K. Whittlesey ◽  
Jonathan M. J. Williams
Keyword(s):  
Bond Activation ◽  
Carbene Complexes ◽  
Alcohol Dehydrogenation

C H Bond activation of 2-isobutylthiazole at C5 position catalysed by Pd-N-heterocyclic carbene complexes

2021 ◽  
Vol 937 ◽  
pp. 121730
Author(s):  
Nesrin Buğday ◽  
Siraj Khan ◽  
Sedat Yaşar ◽  
İsmail Özdemir
Keyword(s):  
Bond Activation ◽  
Carbene Complexes

Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PCcarbeneS Pincer Ligand

2019 ◽  
Vol 38 (21) ◽  
pp. 4093-4104 ◽  
Author(s):  
Lennart T. Scharf ◽  
Alexander Kowsari ◽  
Thorsten Scherpf ◽  
Kai-Stephan Feichtner ◽  
Viktoria H. Gessner
Keyword(s):  
Bond Activation ◽  
Pincer Ligand ◽  
Carbene Complexes

Modulating reactivity in iridium bis(N-heterocyclic carbene) complexes: influence of ring size on E–H bond activation chemistry

2014 ◽  
Vol 43 (32) ◽  
pp. 12288-12298 ◽  
Author(s):  
Nicholas Phillips ◽  
Christina Y. Tang ◽  
Rémi Tirfoin ◽  
Michael J. Kelly ◽  
Amber L. Thompson ◽  
...  
Keyword(s):  
Bond Activation ◽  
Ring Size ◽  
Carbene Complexes

Critical influence of NHC ring size: highly labile [Ir(5-Mes)2(H)2]+can only be studied by trapping experiments, while [Ir(6-Mes)2(H)2]+and [Ir(6-Xyl)2(H)2]+are air/moisture stable.

Silver(i) NHC mediated C–C bond activation of alkyl nitriles and catalytic efficiency in oxazoline synthesis

2015 ◽  
Vol 51 (41) ◽  
pp. 8699-8701 ◽  
Author(s):  
Rachael Heath ◽  
Helge Müller-Bunz ◽  
Martin Albrecht
Keyword(s):  
High Efficiency ◽  
Bond Activation ◽  
Aldol Condensation ◽  
Bond Cleavage ◽  
Catalytic Efficiency ◽  
Carbene Complexes ◽  
Ambient Temperatures ◽  
Mild Conditions ◽  
New Applications

C–C bond cleavage is achieved with silver carbene species under relatively mild conditions (80 °C) stoichiometrically, and aldol condensation is catalyzed at ambient temperatures in high efficiency, with turnover numbers up to 5000 h−1, thus disclosing new applications and synthetic opportunities based on easily accessible silver carbene complexes.

Bond activation by d0 metal carbene complexes in the gas phase

1993 ◽  
Vol 7 (9) ◽  
pp. 844-847 ◽  
Author(s):  
Kimber L. Wilson ◽  
Brian T. Cooper ◽  
Steven W. Buckner
Keyword(s):  
Gas Phase ◽  
Bond Activation ◽  
Carbene Complexes

Cooperative bond activation reactions with carbene complexes

2018 ◽  
Vol 54 (50) ◽  
pp. 6540-6553 ◽  
Author(s):  
Kai-Stephan Feichtner ◽  
Viktoria H. Gessner
Keyword(s):  
Bond Activation ◽  
Carbene Complexes ◽  
Recent Advances ◽  
Metal Ligand

This review highlights the recent advances in the application of carbene complexes in bond activation reactions via metal–ligand cooperation.

Cooperative P–H Bond Activation with Ruthenium and Iridium Carbene Complexes

2016 ◽  
Vol 35 (15) ◽  
pp. 2507-2515 ◽  
Author(s):  
Julia Weismann ◽  
Lennart T. Scharf ◽  
Viktoria H. Gessner
Keyword(s):  
Bond Activation ◽  
Carbene Complexes
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