Toward the Rational Design of Supramolecular Coordination Polymers. The Effect of Solvent and Substituent Changes on the Structure of Self-Assembled Metal-Organometallic Networks

2003 ◽  
Vol 22 (12) ◽  
pp. 2364-2366 ◽  
Author(s):  
Moonhyun Oh ◽  
Gene B. Carpenter ◽  
D. A. Sweigart
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Effect Of Solvent ◽  
Supramolecular Coordination ◽  
Self Assembled

Recent developments in dipyrrin based metal complexes: Self-assembled nanoarchitectures and materials applications

2020 ◽  
Vol 24 (05n07) ◽  
pp. 646-661
Author(s):  
Qian Jiang ◽  
Nicolas Desbois ◽  
Shifa Wang ◽  
Claude P. Gros
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Luminescent Material ◽  
Orbital Ordering ◽  
Heteroleptic Complexes ◽  
Supramolecular Coordination ◽  
Recent Developments ◽  
Potential Applications ◽  
Metal Organic ◽  
Self Assembled

While dipyrrin-boron complexes (BODIPYs) and their derivatives have attracted much attention, dipyrrin-based metal complexes recently appeared as a novel luminescent material. So far, dipyrrin-metal complexes have been regarded as non-luminescent or weakly luminescent. Interestingly, introduction of steric hindrance at the meso-position and the development of heteroleptic complexes with proper frontier orbital ordering are two recent strategies that have been developed to improve their luminescent ability. Compared with BODIPYs, one of the distinctive advantages of dipyrrin-metal complexes is that they can form a series of self-assembled supramolecules and polymer assemblies via facile coordination reactions. In recent times, several supramolecular, coordination polymers and Metal-Organic Frameworks (MOFs) have been developed, [Formula: see text] by spontaneous coordination reactions between dipyrrin ligands and metal ions. As a novel luminescent material, dipyrrin-metal complexes have been applied in many fields. This review article summarizes recent developments in dipyrrin-metal complexes from the viewpoint of the improvement of luminescent ability, the formation of supramolecular and coordination polymers and their potential applications.

A study of the effect of pyridine linkers on the viscosity and electrochromic properties of metallo-supramolecular coordination polymers

2018 ◽  
Vol 6 (13) ◽  
pp. 3310-3321 ◽  
Author(s):  
Sandesh Pai ◽  
Marco Schott ◽  
Lukas Niklaus ◽  
Uwe Posset ◽  
Dirk G. Kurth
Keyword(s):  
Coordination Polymers ◽  
Supramolecular Polymers ◽  
Electrochromic Properties ◽  
Supramolecular Coordination ◽  
Self Assembled

We present the optical, electrochemical, and electrochromic properties of Fe(ii)-, Co(ii)- and Ru(ii)-based metallo-supramolecular polymers (MEPEs) self-assembled from rigid, π-conjugated bis-terpyridines with different numbers of pyridine linkers.

scholarly journals Metal(II) Coordination Polymers from Tetracarboxylate Linkers: Synthesis, Structures, and Catalytic Cyanosilylation of Benzaldehydes

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 204
Author(s):  
Yu Li ◽  
Chumin Liang ◽  
Xunzhong Zou ◽  
Jinzhong Gu ◽  
Marina V. Kirillova ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Polycarboxylic Acid ◽  
X Ray Diffraction ◽  
X Ray ◽  
Trimethylsilyl Cyanide ◽  
Effect Of Solvent ◽  
Highly Active ◽  
Solvent Type ◽  
Metal Organic ◽  
Chloride Salts

Three 2D coordination polymers, [Cu2(µ4-dpa)(bipy)2(H2O)]n∙6nH2O (1), [Mn2(µ6-dpa)(bipy)2]n (2), and [Zn2(µ4-dpa)(bipy)2(H2O)2]n·2nH2O (3), were prepared by a hydrothermal method using metal(II) chloride salts, 3-(2′,4′-dicarboxylphenoxy)phthalic acid (H4dpa) as a linker, as well as 2,2′-bipyridine (bipy) as a crystallization mediator. Compounds 1–3 were obtained as crystalline solids and fully characterized. The structures of 1–3 were established by single-crystal X-ray diffraction, revealing 2D metal-organic networks of sql, 3,6L66, and hcb topological types. Thermal stability and catalytic behavior of 1–3 were also studied. In particular, zinc(II) coordination polymer 3 functions as a highly active and recoverable heterogeneous catalyst in the mild cyanosilylation of benzaldehydes with trimethylsilyl cyanide to give cyanohydrin derivatives. The influence of various parameters was investigated, including a time of reaction, a loading of catalyst and its recycling, an effect of solvent type, and a substrate scope. As a result, up to 93% product yields were attained in a catalyst recoverable and reusable system when exploring 4-nitrobenzaldehyde as a model substrate. This study contributes to widening the types of multifunctional polycarboxylic acid linkers for the design of novel coordination polymers with notable applications in heterogeneous catalysis.

scholarly journals Rational Design of Copper(II)–Uracil Nanoprocessed Coordination Polymers to Improve Their Cytotoxic Activity in Biological Media

2021 ◽  
Author(s):  
Verónica G. Vegas ◽  
Ana Latorre ◽  
María Luisa Marcos ◽  
Carlos J. Gómez-García ◽  
Óscar Castillo ◽  
...  
Keyword(s):  
Cytotoxic Activity ◽  
Coordination Polymers ◽  
Rational Design ◽  
Biological Media

scholarly journals Back Cover: Ferroelectric Coordination Polymers Self-Assembled from Mesogenic Zinc(II) Porphyrin and Dipolar Bridging Ligands (Chem. Eur. J. 40/2016)

2016 ◽  
Vol 22 (40) ◽  
pp. 14408-14408
Author(s):  
Joseph K.-H. Hui ◽  
Hiroyuki Kishida ◽  
Keita Ishiba ◽  
Kenta Takemasu ◽  
Masa-aki Morikawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Bridging Ligands ◽  
Back Cover ◽  
Self Assembled

Carboxylic Acid-Doped SBA-15 Silica as a Host for Metallo-supramolecular Coordination Polymers†

2008 ◽  
Vol 112 (46) ◽  
pp. 14637-14647 ◽  
Author(s):  
D. Akcakayiran ◽  
D. Mauder ◽  
C. Hess ◽  
T. K. Sievers ◽  
D. G. Kurth ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Supramolecular Coordination

Redox-Triggered Folding of Self-Assembled Coordination Polymers incorporating Viologen Units

2018 ◽  
Vol 24 (49) ◽  
pp. 12961-12969 ◽  
Author(s):  
Wathiq Sattar Abdul-Hassan ◽  
Denis Roux ◽  
Christophe Bucher ◽  
Saioa Cobo ◽  
Florian Molton ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembled
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