Ferrocene-Based Heteronuclear Bidentate Lewis Acids via Highly Selectiveortho-Borylation of 1,1‘-Bis(trimethylstannyl)ferrocene

2002 ◽  
Vol 21 (20) ◽  
pp. 4169-4181 ◽  
Author(s):  
Juan A. Gamboa ◽  
Anand Sundararaman ◽  
Lazaros Kakalis ◽  
Alan J. Lough ◽  
Frieder Jäkle
Keyword(s):  
Lewis Acids ◽  
Bidentate Lewis Acids

ChemInform Abstract: Metallocene-Based Bidentate Lewis Acids

ChemInform ◽  
2010 ◽  
Vol 33 (51) ◽  
pp. no-no
Author(s):  
Frieder Jakle
Keyword(s):  
Lewis Acids ◽  
Bidentate Lewis Acids

Bidentate Lewis Acids for the Activation of 1,2-Diazines - A New Mode of Catalysis

2011 ◽  
Vol 2011 (17) ◽  
pp. 3238-3245 ◽  
Author(s):  
Simon N. Kessler ◽  
Markus Neuburger ◽  
Hermann A. Wegner
Keyword(s):  
Lewis Acids ◽  
Bidentate Lewis Acids

Bidentate Lewis acid catalysts in asymmetric synthesis

2002 ◽  
Vol 74 (1) ◽  
pp. 123-128 ◽  
Author(s):  
Keiji Maruoka
Keyword(s):  
Asymmetric Synthesis ◽  
Organic Synthesis ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Asymmetric Induction ◽  
Acid Catalysts ◽  
Lewis Acid Catalysts ◽  
High Chemical ◽  
Bidentate Lewis Acids

The chemistry of bidentate Lewis acids belongs to an unexplored field of science, and so far has been only poorly studied. This paper illustrates the design of several bidentate Al and Ti Lewis acids, and their successful application to selective organic synthesis, particularly to asymmetric synthesis. For example, a new, chiral bidentate Ti(IV) complex is successfully designed by adding commercially available Ti(OPri)4 and (S)-binaphthol sequentially to 2,2'-bis(tritylamino)-4,4'-dichlorobenzophenone in CH2Cl2, and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with allyltributyltin. This chiral bidentate Ti(IV) catalyst exhibits uniformly high asymmetric induction as well as high chemical yields for various aldehydes. The present enantioselective allylation is highly chemoselective in the presence of other carbonyl moieties.

scholarly journals Bidentate Lewis Acids Derived from o ‐Diethynylbenzene with Group 13 and 14 Functions

ChemistryOpen ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 1020-1027
Author(s):  
Jens Rudlof ◽  
Niklas Aders ◽  
Jan‐Hendrik Lamm ◽  
Beate Neumann ◽  
Hans‐Georg Stammler ◽  
...  
Keyword(s):  
Lewis Acids ◽  
Group 13 ◽  
Bidentate Lewis Acids

Complexes of Strong Bidentate Lewis Acids Derived from 2,2‘-(1,3-Butadiyne-1,4-diyl)bis[phenol]

1998 ◽  
Vol 17 (6) ◽  
pp. 1128-1133 ◽  
Author(s):  
Okba Saied ◽  
Michel Simard ◽  
James D. Wuest
Keyword(s):  
Lewis Acids ◽  
Bidentate Lewis Acids

o-Bis(haloorganostannyl)benzenes As Powerful Bidentate Lewis Acids toward Halide Ions†

1998 ◽  
Vol 17 (26) ◽  
pp. 5858-5866 ◽  
Author(s):  
Reiner Altmann ◽  
Klaus Jurkschat ◽  
Markus Schürmann ◽  
Dainis Dakternieks ◽  
Andrew Duthie
Keyword(s):  
Lewis Acids ◽  
Halide Ions ◽  
Bidentate Lewis Acids

Geminal bis(haloorganostannanes) and their complexation as mono- and bidentate Lewis acids with dimethyl sulfoxide

1983 ◽  
Vol 2 (1) ◽  
pp. 106-114 ◽  
Author(s):  
Thomas J. Karol ◽  
John P. Hutchinson ◽  
Jeffrey R. Hyde ◽  
Henry G. Kuivila ◽  
Jon A. Zubieta
Keyword(s):  
Dimethyl Sulfoxide ◽  
Lewis Acids ◽  
Bidentate Lewis Acids
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