Influence of Chelating Phosphines on the Insertion of Isocyanides into Palladium−Methyl Bonds in (P−P)Pd(Me)Cl Complexes and Their Further Reaction with Olefins and Isothiocyanates

2002 ◽  
Vol 21 (22) ◽  
pp. 4799-4807 ◽  
Author(s):  
Gareth R. Owen ◽  
Ramón Vilar ◽  
Andrew J. P. White ◽  
David J. Williams
Keyword(s):  
Chelating Phosphines

New water soluble chelating phosphines for aqueous phase catalysis

1997 ◽  
Vol 124 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Hao Ding ◽  
Jianxing Kang ◽  
Brian E. Hanson ◽  
Christian W. Kohlpaintner
Keyword(s):  
Aqueous Phase ◽  
Water Soluble ◽  
Chelating Phosphines ◽  
Aqueous Phase Catalysis

Olefin Oligomerization and Isomerization Catalysts. The Preparation, Properties and Catalytic Action of Dithio Nickel(II) Complexes With Chelating Phosphines

1986 ◽  
Vol 39 (7) ◽  
pp. 1129 ◽  
Author(s):  
KJ Cavell ◽  
AF Masters
Keyword(s):  
Double Bond ◽  
General Formula ◽  
Nickel Complexes ◽  
High Specificity ◽  
Catalytic Action ◽  
Chelating Phosphines ◽  
Olefin Oligomerization ◽  
Double Bond Shift

The syntheses and properties of cationic nickel complexes containing dithio-β-diketonate and chelating bisphosphine ligands of general formula [Ni{R1C(S)CR2C(S)R3}{(PL1L2)R(PL3L4)}]X(Rj,Lj = alkyl or aryl, R = (CH2)n, n = 1-4, X = halide, BPh4, PF6, etc.) are described. The compounds are shown to be effective catalysts for the oligomerization and double bond shift isomerization of olefins with a high specificity for dimeric products rich in desirable linear and near linear isomers.

scholarly journals Synthetic and structural studies of phosphine coordinated boronium salts

2017 ◽  
Vol 46 (22) ◽  
pp. 7291-7308 ◽  
Author(s):  
Anthony F. Hill ◽  
Jas S. Ward
Keyword(s):  
Structural Studies ◽  
Chelating Phosphines

The reactions of BrH2B·SMe2 or Br2HB·SMe2 with a variety of primary, secondary, tertiary and chelating phosphines affords a range of boronium salts of the form [HXB(PR3)2]Br (X = H, Br), e.g., the ferrocenophane shown. The equilibrium between such species and the neutral haloborane adducts HXBr(PR3) is discussed.

Neutral mononuclear luminescent Pd(II) complexes with heterocyclic thiolate ligands and chelating phosphines. Structural and photophysical assignments

Polyhedron ◽  
2015 ◽  
Vol 94 ◽  
pp. 67-74 ◽  
Author(s):  
P.A. Papanikolaou ◽  
A.G. Papadopoulos ◽  
A. Hatzidimitriou ◽  
P. Aslanidis
Keyword(s):  
Thiolate Ligands ◽  
Chelating Phosphines

Bridging rather than chelation in the substitution chemistry of the osmium(I) complex [Os2(MeCO2)2(CO)6] with potentially chelating phosphines and arsines

Polyhedron ◽  
1989 ◽  
Vol 8 (12) ◽  
pp. 1537-1544 ◽  
Author(s):  
Antony J. Deeming ◽  
Didier Nuel ◽  
Neil P. Randle ◽  
Caroline Whittaker
Keyword(s):  
Substitution Chemistry ◽  
Chelating Phosphines

Nitrido-technetium and -rhenium complexes with chelating phosphines: synthesis, reactivity and crystal structures

1993 ◽  
pp. 1281 ◽  
Author(s):  
Andrea Marchi ◽  
Lorenza Marvelli ◽  
Roberto Rossi ◽  
Luciano Magon ◽  
Licia Uccelli ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Rhenium Complexes ◽  
Chelating Phosphines

α-Dicationic Chelating Phosphines: Synthesis and Application to the Hydroarylation of Dienes

2017 ◽  
Vol 139 (13) ◽  
pp. 4948-4953 ◽  
Author(s):  
Lianghu Gu ◽  
Lawrence M. Wolf ◽  
Adam Zieliński ◽  
Walter Thiel ◽  
Manuel Alcarazo
Keyword(s):  
Chelating Phosphines
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