Synthesis and Molecular Structure of a Palladium Complex Containing a λ5-Phosphinine-Based SPS Pincer Ligand

2002 ◽  
Vol 21 (13) ◽  
pp. 2785-2788 ◽  
Author(s):  
Marjolaine Doux ◽  
Claire Bouet ◽  
Nicolas Mézailles ◽  
Louis Ricard ◽  
Pascal Le Floch
Keyword(s):  
Molecular Structure ◽  
Palladium Complex ◽  
Pincer Ligand

scholarly journals X-RAY MOLECULAR STRUCTURE OF A PYRIDYL-BRIDGED DINUCLEAR PALLADIUM COMPLEX,trans(P,N)-[PdBr(μ-C5H4N-C2,N)(PPh3)]2

1980 ◽  
Vol 9 (8) ◽  
pp. 913-914 ◽  
Author(s):  
Kazumi Nakatsu ◽  
Kenji Kinoshita ◽  
Hitoshi Kanda ◽  
Kiyoshi Isobe ◽  
Yukio Nakamura ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Palladium Complex ◽  
X Ray

scholarly journals Crystal structure of unsymmetrical α-diimine palladium(II) complex cis-[{ArN=C(Me)–(Et)C=NAr}PdCl2] [Ar = 2,6-(iPr)2C6H3]

2017 ◽  
Vol 73 (8) ◽  
pp. 1148-1150
Author(s):  
Shravan Kumar Ellandula ◽  
Cosmos Opoku Amoako ◽  
Joel T. Mague ◽  
Perumalreddy Chandrasekaran
Keyword(s):  
Molecular Structure ◽  
Palladium Complex ◽  
Crystal And Molecular Structure ◽  
Chelate Ring ◽  
X Ray Diffraction ◽  
X Ray ◽  
Square Planar ◽  
Diimine Ligand ◽  
Coordination Plane ◽  
N Vector

The unsymmetrical α-diimine ligand N-{2-[2,6-bis(propan-2-yl)phenylimino]pentan-3-ylidene}-2,6-bis(propan-2-yl)aniline, [ArN=C(Me)—(Et)C=NAr] [Ar = 2,6-(iPr)2C6H3], (I), and the corresponding palladium complex, cis-(N-{2-[2,6-bis(propan-2-yl)phenylimino]pentan-3-ylidene}-2,6-bis(propan-2-yl)aniline)dichloridopalladium(II) 1,2-dichloroethane monosolvate, [PdCl2(C29H42N2)]·C2H4Cl2 or cis[PdCl2{I}], (II), have been synthesized and characterized. The crystal and molecular structure of the palladium(II) complex have been established by single-crystal X-ray diffraction. The compound crystallized along with a 1,2-dichloroethane solvent of crystallization. The coordination plane of the PdII atom shows a slight tetrahedral distortion from square-planar, as indicated by the dihedral angle between the PdCl2 and PdN2 planes of 4.19 (8)°. The chelate ring is folded along the N...N vector by 7.1 (1)°.

Synthesis and Molecular Structure of a Perfluoroalkyl Complex of Platinum Containing a PCP Pincer Ligand

2001 ◽  
Vol 20 (22) ◽  
pp. 4741-4744 ◽  
Author(s):  
Russell P. Hughes ◽  
Alex Williamson ◽  
Christopher D. Incarvito ◽  
Arnold L. Rheingold
Keyword(s):  
Molecular Structure ◽  
Pincer Ligand ◽  
Pcp Pincer

The molecular structure of a thia-allyl palladium complex at—160°C and 20°C

1981 ◽  
Vol 208 (3) ◽  
pp. 407-418 ◽  
Author(s):  
Kunio Miki ◽  
Nobuo Tanaka ◽  
Nobutami Kasai
Keyword(s):  
Molecular Structure ◽  
Palladium Complex
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