Bond Angle Effects on the Migratory Insertion of Ethylene and Carbon Monoxide into Palladium(II)−Methyl Bonds in Complexes Bearing Bidentate Phosphine Ligands

2001 ◽  
Vol 20 (25) ◽  
pp. 5266-5276 ◽  
Author(s):  
John Ledford ◽  
C. Scott Shultz ◽  
Derek P. Gates ◽  
Peter S. White ◽  
Joseph M. DeSimone ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Bond Angle ◽  
Phosphine Ligands ◽  
Migratory Insertion ◽  
Bidentate Phosphine

scholarly journals Efficient photorelease of carbon monoxide from a luminescent tricarbonyl rhenium(i) complex incorporating pyridyl-1,2,4-triazole and phosphine ligands

2021 ◽  
Author(s):  
Ángel D. Hernández Mejías ◽  
Alexandre Poirot ◽  
Meriem Rmili ◽  
Nadine Leygue ◽  
Mariusz Wolff ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Colour Change ◽  
Phosphine Ligands

In this new Re(i) PhotoCORM, the efficient photoproduction of carbon monoxide is visualized through a strong colour change of the emitted phosphorescence.

Mono- and Bidentate Phosphine Ligands in the Palladium-Catalyzed Methyl Acrylate Dimerization

2003 ◽  
Vol 345 (3) ◽  
pp. 402-409 ◽  
Author(s):  
Jörg Zimmermann ◽  
Igor Tkatchenko ◽  
Peter Wasserscheid
Keyword(s):  
Methyl Acrylate ◽  
Phosphine Ligands ◽  
Palladium Catalyzed ◽  
Bidentate Phosphine

Coordination chemistry of bidentate phosphine ligands with hydrogen-bonding arms: Picket-fence rhodium complexes

Polyhedron ◽  
2014 ◽  
Vol 69 ◽  
pp. 156-159 ◽  
Author(s):  
Ilknur Babahan ◽  
James T. Engle ◽  
Nishant Kumar ◽  
Christopher J. Ziegler ◽  
Li Jia
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Chemistry ◽  
Phosphine Ligands ◽  
Rhodium Complexes ◽  
Picket Fence ◽  
Bidentate Phosphine

Synthesis of poly(ether ketone amide)s by a heterogeneous palladium-catalyzed polycondensation of aromatic diiodides, diamines, and carbon monoxide

2018 ◽  
Vol 31 (4) ◽  
pp. 425-437 ◽  
Author(s):  
Bin Huang ◽  
Pingping Wang ◽  
Xiaojun Zhu ◽  
Mingzhong Cai
Keyword(s):  
Carbon Monoxide ◽  
Palladium Complex ◽  
Significant Loss ◽  
Aromatic Diamines ◽  
Glass Transition Temperatures ◽  
External Magnet ◽  
Palladium Catalyzed ◽  
Bidentate Phosphine ◽  
Ether Ketone ◽  
Heterogeneous Palladium Catalyst

A series of novel aromatic poly(ether ketone amide)s (PEKAs) were synthesized by the heterogeneous palladium-catalyzed carbonylative polycondensation of aromatic diiodides with ether ketone units, aromatic diamines, and carbon monoxide in N, N-dimethylacetamide (DMAc) at 120°C using 6 mol% of a magnetic nanoparticles–supported bidentate phosphine palladium complex (Fe3O4@SiO2-2P-PdCl2) as catalyst and 1,8-diazabicyclo[5,4,0]-7-undecene as base. The PEKAs had inherent viscosities ranging from 0.61 dl g−1 to 0.75 dl g−1. All the PEKAs were soluble in strong dipolar organic solvents. These PEKAs showed glass transition temperatures between 178°C and 232°C and 10% weight loss temperatures ranging from 443°C to 496°C in nitrogen. These PEKAs could be cast into transparent, flexible, and strong films from DMAc solutions with tensile strengths of 72.8–82.6 MPa, tensile moduli of 2.19–2.84 GPa, and elongations at break of 5.4–7.5%. Importantly, the heterogeneous palladium catalyst can be conveniently recovered from the reaction mixture by simply applying an external magnet and recycled up to eight times without significant loss of activity.

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