Unusual Reactivity of “Proton Sponge” as a Hydride Donor to Transition Metals:  Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III)

Russell P. Hughes; Ivan Kovacik; Danielle C. Lindner; Jeremy M. Smith; Stefan Willemsen; Donghui Zhang; Ilia A. Guzei; Arnold L. Rheingold

doi:10.1021/om0102347

Unusual Reactivity of “Proton Sponge” as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III)

Organometallics ◽

10.1021/om0102347 ◽

2001 ◽

Vol 20 (14) ◽

pp. 3190-3197 ◽

Cited By ~ 31

Author(s):

Russell P. Hughes ◽

Ivan Kovacik ◽

Danielle C. Lindner ◽

Jeremy M. Smith ◽

Stefan Willemsen ◽

...

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Proton Sponge

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Structural characterization of heterometallic platinum complexes with non-transition metals. Part II: heterotrimeric complexes

Main Group Metal Chemistry ◽

10.1515/mgmc-2012-0062 ◽

2013 ◽

Vol 36 (1-2) ◽

pp. 1-10 ◽

Cited By ~ 1

Author(s):

Milan Melník ◽

Peter Mikuš

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Platinum Complexes

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Multiple bonds between main-group elements and transition metals. 48. Synthesis and structural characterization of trioxo(.eta.5-ethyltetramethylcyclopentadienyl)rhenium, a half-sandwich complex of heptavalent rhenium

Inorganic Chemistry ◽

10.1021/ic00280a032 ◽

1988 ◽

Vol 27 (7) ◽

pp. 1254-1257 ◽

Cited By ~ 21

Author(s):

Jun Okuda ◽

Eberhardt Herdtweck ◽

Wolfgang A. Herrmann

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Main Group ◽

Sandwich Complex ◽

Multiple Bonds ◽

Main Group Elements ◽

Half Sandwich

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Structural Characterization of Neutral Saccharides by Negative Ion MALDI Mass Spectrometry Using a Superbasic Proton Sponge as Deprotonating Matrix

Journal of the American Society for Mass Spectrometry ◽

10.1007/s13361-017-1679-y ◽

2017 ◽

Vol 28 (8) ◽

pp. 1666-1675 ◽

Cited By ~ 14

Author(s):

Cosima Damiana Calvano ◽

Tommaso R. I. Cataldi ◽

Julius F. Kögel ◽

Antonio Monopoli ◽

Francesco Palmisano ◽

...

Keyword(s):

Mass Spectrometry ◽

Structural Characterization ◽

Maldi Mass Spectrometry ◽

Negative Ion ◽

Proton Sponge

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Structural characterization of [(μ-H)Os3(CO)10(μ-NH2)] and a new polymorphic form of [(μ-H)Os3(CO)10(μ-SH)]. Influence of the bridging group on the geometry of compounds [(μ-H)Os3(CO)10(μ-X)] (X=NH2, NRH, PRH, SbR2, OH, SH, SR, SeR, Cl, Br). Reactions of [(μ-H)Os3(CO)10(μ-X)] (X=OH and SH) with proton sponge

Journal of Molecular Structure ◽

10.1016/j.molstruc.2010.10.033 ◽

2011 ◽

Vol 985 (2-3) ◽

pp. 134-138 ◽

Cited By ~ 5

Author(s):

Ottmar R. Reyes-López ◽

Marco A. Leyva ◽

María J. Rosales-Hoz

Keyword(s):

Structural Characterization ◽

Polymorphic Form ◽

Proton Sponge

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Phosphino macrocycles. 15. Structural characterization of tridentate 11-membered phosphino macrocyclic complexes of transition metals. Examples of octahedral, square-pyramidal, and tetrahedral geometries

Inorganic Chemistry ◽

10.1021/ic00220a041 ◽

1985 ◽

Vol 24 (26) ◽

pp. 4629-4634 ◽

Cited By ~ 23

Author(s):

Evan P. Kyba ◽

Raymond E. Davis ◽

Shiuh Tzung Liu ◽

Karen A. Hassett ◽

Steven B. Larson

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Macrocyclic Complexes ◽

Complexes Of Transition Metals

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Structural characterization of tripodal phosphine complexes of transition metals. Examples of chair and twisted-boat conformations in six-membered chelate rings

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(90)87302-t ◽

1990 ◽

Vol 387 (1) ◽

pp. 83-94 ◽

Cited By ~ 13

Author(s):

Shiuh-Tzung Liu ◽

Gwo-Jiun Liu ◽

Chien-Hung Yieh ◽

Ming-Chu Cheng ◽

Shie-Ming Peng

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Phosphine Complexes ◽

Complexes Of Transition Metals ◽

Twisted Boat ◽

Chelate Rings

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ChemInform Abstract: Multiple Bonds Between Main-Group Elements and Transition Metals. Part 48. Synthesis and Structural Characterization of Trioxo(η5-ethyltetramethylcyclopentadienyl)rhenium, a Half-Sandwich Complex of Heptavalent Rhenium.

ChemInform ◽

10.1002/chin.198831248 ◽

1988 ◽

Vol 19 (31) ◽

Author(s):

J. OKUDA ◽

E. HERDTWECK ◽

W. A. HERRMANN

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Main Group ◽

Sandwich Complex ◽

Multiple Bonds ◽

Main Group Elements ◽

Half Sandwich

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Synthesis and Structural Characterization of Heterobimetallic Bismuth Complexes with Main Group and Transition Metals

Organometallics ◽

10.1021/om900623w ◽

2009 ◽

Vol 28 (19) ◽

pp. 5733-5738 ◽

Cited By ~ 9

Author(s):

Bijan Nekoueishahraki ◽

Anukul Jana ◽

Herbert W. Roesky ◽

Lallan Mishra ◽

Daniel Stern ◽

...

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Main Group

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ChemInform Abstract: Phosphino Macrocycles. Part 15. Structural Characterization of Tridentate 11-Membered Phosphino Macrocyclic Complexes of Transition Metals.

Chemischer Informationsdienst ◽

10.1002/chin.198617061 ◽

1986 ◽

Vol 17 (17) ◽

Author(s):

E. P. KYBA ◽

R. E. DAVIS ◽

S.-T. LIU ◽

K. A. HASSETT ◽

S. B. LARSON

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Macrocyclic Complexes ◽

Complexes Of Transition Metals

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Complexes of Lapachol and Lawsone with Lanthanides

Natural Product Communications ◽

10.1177/1934578x1501001105 ◽

2015 ◽

Vol 10 (11) ◽

pp. 1934578X1501001

Author(s):

Salvatore Genovese ◽

Vito Alessandro Taddeo ◽

Francesco Epifano ◽

Serena Fiorito

Keyword(s):

Transition Metals ◽

Structural Characterization ◽

Preliminary Data ◽

Short Communication ◽

Naturally Occurring ◽

Cytotoxic Compounds ◽

First Time

Naturally occurring 2-hydroxy-1,4-naphthoquinones are well known to form readily stable complexes with transition metals. In this short communication we describe for the first time the synthesis and preliminary data about structural characterization of complexes between two naturally widespread 2-hydroxy-1,4-naphthoquinones, namely lapachol (1) and lawsone (2), with selected lanthanides like lanthanum, gadolinium, and ytterbium. When tested as cytotoxic compounds, such complexes exhibited an activity that was either higher or equal to that of the parent naphthoquinone.

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