Lewis Acid−Base Adducts of Pentamethylcyclopentadienylgallium with Trivalent Group 13-Element Compounds

2001 ◽  
Vol 20 (13) ◽  
pp. 2854-2858 ◽  
Author(s):  
Peter Jutzi ◽  
Beate Neumann ◽  
Guido Reumann ◽  
Lars Oliver Schebaum ◽  
Hans-Georg Stammler
Keyword(s):  
Lewis Acid ◽  
Acid Base ◽  
Group 13

scholarly journals Structure investigations of group 13 organometallic carboxylates

2017 ◽  
Vol 46 (3) ◽  
pp. 669-677 ◽  
Author(s):  
Iwona Justyniak ◽  
Daniel Prochowicz ◽  
Adam Tulewicz ◽  
Wojciech Bury ◽  
Piotr Goś ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Lewis Acid ◽  
Relative Magnitude ◽  
Lewis Base ◽  
Acid Base ◽  
Group 13 ◽  
Structure Investigations

The effect of both the relative magnitude of electrophilicity of metal centres and the character of a Lewis base on the molecular structure of the electron-precise [R2M(μ-O2CPh)]2-type carboxylates and their Lewis acid–base adducts [(R2M)(μ-O2CPh)(py-Me)] is reported.

scholarly journals Lewis acid–base adducts of group 13 elements: synthesis, structure and reactivity toward benzaldehyde

2016 ◽  
Vol 45 (28) ◽  
pp. 11437-11444 ◽  
Author(s):  
C. Ganesamoorthy ◽  
M. Matthias ◽  
D. Bläser ◽  
C. Wölper ◽  
S. Schulz
Keyword(s):  
Lewis Acid ◽  
Acid Base ◽  
Group 13

[LGa-M(C6F5)3] (M = B 1, Al 2, Ga 3) reacts with benzaldehyde in different ways including the formation of the zwitterionic species [LGa(C6F5){CH(Ph)(OAl(C6F5)2)}] (5).

scholarly journals Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights

2017 ◽  
Vol 46 (3) ◽  
pp. 854-864 ◽  
Author(s):  
Melissa M. Wu ◽  
Arran M. Gill ◽  
Lu Yunpeng ◽  
Li Yongxin ◽  
Rakesh Ganguly ◽  
...  
Keyword(s):  
Structural Stability ◽  
Lewis Acid ◽  
Heterocyclic Carbenes ◽  
Theoretical Studies ◽  
Acid Base ◽  
Group 13 ◽  
Factors Affecting ◽  
The Stability

Treatment of aromatic N-substituted N-heterocyclic carbenes (NHCs) with trimethylgallium and -indium yielded the new Lewis acid–base adducts (as shown in the Figure). The steric and electronic factors affecting the stability of these complexes were quantified using percent buried volume, topographic steric maps and theoretical studies.

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Chalcogen versus Dative Bonding in [SF3]+ Lewis Acid–Base Adducts: [SF3(NCCH3)2]+, [SF3(NC5H5)2]+, and [SF3(phen)]+ (phen = 1,10-phenanthroline)

2021 ◽  
Vol 60 (6) ◽  
pp. 3893-3901
Author(s):  
Douglas Turnbull ◽  
Praveen Chaudhary ◽  
Paul Hazendonk ◽  
Stacey D. Wetmore ◽  
Michael Gerken
Keyword(s):  
Lewis Acid ◽  
Acid Base
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