Synthesis and X-ray Crystal Structures of Pnictogen-Bridged, Bimetallic Complexes Containing Main Group Metal and Tricarbonylnickel Fragments

2001 ◽  
Vol 20 (11) ◽  
pp. 2405-2408 ◽  
Author(s):  
Florian Thomas ◽  
Stephan Schulz ◽  
Martin Nieger
Keyword(s):  
Crystal Structures ◽  
Main Group ◽  
Bimetallic Complexes ◽  
X Ray ◽  
Group Metal ◽  
Main Group Metal

Novel isomorphism of two hexagonal non-centrosymmetric hybrid crystals of M(en)3Ag2I4 (M = transition metal Mn2+ or main-group metal Mg2+; en = ethylenediamine)

CrystEngComm ◽  
2018 ◽  
Vol 20 (3) ◽  
pp. 356-361 ◽  
Author(s):  
Xin Chen ◽  
Zhi-Yuan Yao ◽  
Chen Xue ◽  
Zhu-Xi Yang ◽  
Jian-Lan Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Hybrid Crystals ◽  
First Time

For the first time, a main-group metal complex is used as a template for the formation of hybrid crystal structures and isomorphic hybrid crystals are obtained using transition and main-group metal complexes.

Syntheses, crystal structures, and luminescence of two main-group metal complexes based on 3,4-pyrazoledicarboxylic acid

2012 ◽  
Vol 65 (6) ◽  
pp. 923-933 ◽  
Author(s):  
Li-Dong Wang ◽  
Feng Tao ◽  
Mei-Ling Cheng ◽  
Qi Liu ◽  
Wei Han ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal

Lewis-Base Adducts of Main Group Metal(I) Compounds. XI. Di-μ-iodo-bis(N,N,N′,N″,N″-pentamethyldiethylenetriamine-N,N′,N″-sodium)

1989 ◽  
Vol 42 (8) ◽  
pp. 1393 ◽  
Author(s):  
CL Raston ◽  
CR Whitaker ◽  
AH White
Keyword(s):  
Single Crystal ◽  
Structural Characterization ◽  
Structure Determination ◽  
Main Group ◽  
Lewis Base ◽  
Coordination Complex ◽  
X Ray ◽  
Group Metal ◽  
Main Group Metal

The synthesis and structural characterization of the 1:1 adduct of sodium(I) iodide and N,N,N′,N″,N″- pentamethyldiethylenetriamine (pmdeta), a novel coordination complex of sodium(I), is recorded. Single-crystal X-ray structure determination shows the compound to be a �,�′- diiodo-bridged dimer, with the tridentate base making up the five-coordinate environment of sodium: [( pmdeta )NaI2Na( pmdeta )]. Crystals are triclinic, P1, a 10.113(2),b 9.470(2), c 8.793(4) � , α 114.48(2), β 92.09(2), γ 96-65(1)°, Z= 1 dimer ; R was 0.037 for 1837 'observed' reflections.

Über Verbindungen subvalenter Hauptgruppenmetallkationen mit Dithiolaten, 3. Mitteilung [1]. Die Kristallstruktur von [As(C6H5)4]2[Pb(S2C=C(CN)2)2]/Compounds of Subvalent Main Group Metal Cations with Dithiolates, Part 3 [1] Crystal Structure of [As(C6H5)4]2[Pb(S2C=C(CN)2)2]

1989 ◽  
Vol 44 (3) ◽  
pp. 293-295 ◽  
Author(s):  
Hans-Ulrich Hummel ◽  
Hermann Meske
Keyword(s):  
Crystal Structure ◽  
Complex Anion ◽  
Lone Pair ◽  
Metal Cations ◽  
Main Group ◽  
X Ray Diffraction ◽  
X Ray ◽  
Group Metal ◽  
Main Group Metal

The crystal structure of [AsPh4]2[Pb(S2C=C(CN)2)2] has been determined by X-ray diffraction. In the pyramidal complex anion [Pb(S2C=C(CN)2)2]2- Pb is coordinated to the sulfur atoms of the dithiolates. The geometry is indicative for a stereochemically active lone-pair at the apex of the square pyramid.

Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C

2021 ◽  
Author(s):  
Tatyana S. Koptseva ◽  
Vladimir G. Sokolov ◽  
Sergey Yu. Ketkov ◽  
Elena A. Rychagova ◽  
Anton V. Cherkasov ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Complexes ◽  
Main Group ◽  
Group Metal ◽  
Reversible Addition ◽  
Main Group Metal
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