NewC2v- and ChiralC2-Symmetric Olefin Polymerization Catalysts Based on Nickel(II) and Palladium(II) Diimine Complexes Bearing 2,6-Diphenyl Aniline Moieties:  Synthesis, Structural Characterization, and First Insight into Polymerization Properties

2001 ◽  
Vol 20 (11) ◽  
pp. 2321-2330 ◽  
Author(s):  
Markus Schmid ◽  
Robert Eberhardt ◽  
Martti Klinga ◽  
Markku Leskelä ◽  
Bernhard Rieger
Keyword(s):  
Structural Characterization ◽  
Olefin Polymerization ◽  
Polymerization Catalysts ◽  
Diimine Complexes ◽  
Insight Into

scholarly journals Insight into Oxide-Bridged Heterobimetallic Al/Zr Olefin Polymerization Catalysts

2016 ◽  
Vol 22 (48) ◽  
pp. 17450-17459 ◽  
Author(s):  
Cédric Boulho ◽  
Harmen S. Zijlstra ◽  
Alexander Hofmann ◽  
Peter H. M. Budzelaar ◽  
Sjoerd Harder
Keyword(s):  
Olefin Polymerization ◽  
Polymerization Catalysts ◽  
Insight Into

[ONNO]-type amine bis(phenolate)-based vanadium catalysts for ethylene homo- and copolymerization

2009 ◽  
Vol 81 (7) ◽  
pp. 1205-1215 ◽  
Author(s):  
Christian Lorber
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Olefin Polymerization ◽  
Oxidation States ◽  
Vanadium Complexes ◽  
Good Activity ◽  
Polymerization Catalysts ◽  
Vanadium Catalysts ◽  
Comonomer Content

The synthesis and solution and solid-state structural characterization of a family of amine bis(phenolate) [ONNO]-vanadium complexes is reviewed. These compounds have oxidation states ranging from vanadium(II) to vanadium(V), and were evaluated as olefin polymerization catalysts. In association with EtAlCl2 cocatalyst, we studied the homopolymerization of ethylene, propene, and 1-hexene, as well as the copolymerization of ethylene with α-olefins (1-hexene, 1-octene) and cycloolefins (norbornene, cyclopentene). Some of these catalysts were shown to produce copolymers with a good activity and comonomer content.

Highly Efficient Carborane-Based Activators for Molecular Olefin Polymerization Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 3335-3342
Author(s):  
S. Olivia Gunther ◽  
Qingheng Lai ◽  
Todd Senecal ◽  
Rafael Huacuja ◽  
Sean Bremer ◽  
...  
Keyword(s):  
Olefin Polymerization ◽  
Polymerization Catalysts ◽  
Highly Efficient

Indium-Bridged Chelating Diamide Group IV Metal Olefin Polymerization Catalysts

2002 ◽  
Vol 21 (10) ◽  
pp. 2145-2148 ◽  
Author(s):  
Jasson T. Patton ◽  
Marilyn M. Bokota ◽  
Khalil A. Abboud
Keyword(s):  
Olefin Polymerization ◽  
Group Iv ◽  
Polymerization Catalysts

Structure/Properties Relationship for Bis(phenoxyamine)Zr(IV)-Based Olefin Polymerization Catalysts: A Simple DFT Model To Predict Catalytic Activity

2012 ◽  
Vol 45 (10) ◽  
pp. 4046-4053 ◽  
Author(s):  
Gianluca Ciancaleoni ◽  
Natascia Fraldi ◽  
Roberta Cipullo ◽  
Vincenzo Busico ◽  
Alceo Macchioni ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Olefin Polymerization ◽  
Polymerization Catalysts ◽  
Dft Model ◽  
Structure Properties

Pyridinylimine-based nickel(II) and palladium(II) complexes: preparation, structural characterization and use as alkene polymerization catalysts

2000 ◽  
Vol 606 (2) ◽  
pp. 112-124 ◽  
Author(s):  
Timo V Laine ◽  
Ulla Piironen ◽  
Kristian Lappalainen ◽  
Martti Klinga ◽  
Erkki Aitola ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Polymerization Catalysts ◽  
Alkene Polymerization

scholarly journals Insights into the activation of silica-supported metallocene olefin polymerization catalysts by methylaluminoxane

2019 ◽  
Vol 334 ◽  
pp. 223-230 ◽  
Author(s):  
Marjolein E.Z. Velthoen ◽  
Jelle M. Boereboom ◽  
Rosa E. Bulo ◽  
Bert M. Weckhuysen
Keyword(s):  
Olefin Polymerization ◽  
Polymerization Catalysts
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