Formation, reactions, and solution dynamics of [M(.eta.1-C5H4R)(C6H4-2-X)(PEt3)2] (M = palladium, platinum)

1990 ◽  
Vol 9 (9) ◽  
pp. 2568-2574 ◽  
Author(s):  
Gordon K. Anderson ◽  
Douglas M. Black ◽  
Ronald J. Cross ◽  
Fraser J. Robertson ◽  
David S. Rycroft ◽  
...  
Keyword(s):  
Solution Dynamics ◽  
Palladium Platinum

Two-Dimensional Infrared Spectroscopy From the Gas to Liquid Phase: Density Dependent J-Scrambling, Vibrational Relaxation, and the Onset of Liquid Character

2019 ◽  
Author(s):  
Greg Ng Pack ◽  
Matthew Rotondaro ◽  
Parth Shah ◽  
Aritra Mandal ◽  
Shyamsunder Erramilli ◽  
...  
Keyword(s):  
Vibrational Energy ◽  
Rotational Relaxation ◽  
Vibrational Energy Relaxation ◽  
Pump Probe ◽  
Solution Dynamics ◽  
Supercritical Phase ◽  
Supercritical Solution ◽  
Asymmetric Stretch ◽  
Two Dimensional Infrared Spectroscopy ◽  
Vibrational Equilibrium

Ultrafast 2DIR spectra and pump-probe responses of the N2O n 3 asymmetric stretch in SF6 as a function of density from the gas to supercritical phase and liquid are reported. 2DIR spectra unequivocally reveal free rotor character at all densities studied in the gas and supercritical region. Analysis of the 2DIR spectra determines that J-scrambling or rotational relaxation in N2O is highly efficient, occurring in ~1.5 to ~2 collisions with SF6 at all non-liquid densities. In contrast, N2O n 3 vibrational energy relaxation requires ~15 collisions, and complete vibrational equilibrium occurs on the ~ns scale at all densities. An independent binary collision model is sufficient to describe these supercritical state point dynamics. The N2O n 3 in liquid SF6 2DIR spectrum shows no evidence of free rotor character or spectral diffusion. Using these 2DIR results, hindered rotor or liquid-like character is found in gas and all supercritical solutions for SF6 densities ³ r * = 0.3, and increases with SF6 density. 2DIR spectral analysis offers direct time domain evidence of critical slowing for SF6 solutions closest to the critical point density. Applications of 2DIR to other high density and supercritical solution dynamics and descriptions are discussed. <br>

scholarly journals On the Use of Iron in Organic Chemistry

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1349 ◽  
Author(s):  
Arnar Guðmundsson ◽  
Jan-E. Bäckvall
Keyword(s):  
Organic Chemistry ◽  
Redox Potential ◽  
Potential Range ◽  
Coupling Reactions ◽  
Base Metals ◽  
Metal Catalysis ◽  
Iron Catalysis ◽  
Cross Coupling Reactions ◽  
Life On Earth ◽  
Palladium Platinum

Transition metal catalysis in modern organic synthesis has largely focused on noble transition metals like palladium, platinum and ruthenium. The toxicity and low abundance of these metals, however, has led to a rising focus on the development of the more sustainable base metals like iron, copper and nickel for use in catalysis. Iron is a particularly good candidate for this purpose due to its abundance, wide redox potential range, and the ease with which its properties can be tuned through the exploitation of its multiple oxidation states, electron spin states and redox potential. This is a fact made clear by all life on Earth, where iron is used as a cornerstone in the chemistry of living processes. In this mini review, we report on the general advancements in the field of iron catalysis in organic chemistry covering addition reactions, C-H activation, cross-coupling reactions, cycloadditions, isomerization and redox reactions.

CO Oxidation and Site Speciation for Alloyed Palladium–Platinum Model Catalysts Studied by in Situ FTIR Spectroscopy

2017 ◽  
Vol 121 (47) ◽  
pp. 26321-26329 ◽  
Author(s):  
Natalia M. Martin ◽  
Magnus Skoglundh ◽  
Gudmund Smedler ◽  
Agnes Raj ◽  
David Thompsett ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Ftir Spectroscopy ◽  
Model Catalysts ◽  
In Situ Ftir ◽  
In Situ Ftir Spectroscopy ◽  
Palladium Platinum

Discovery of a palladium-platinum-gold-mercury bitumen in the Boss Mine, Clark County, Nevada

1999 ◽  
Vol 94 (7) ◽  
pp. 1163-1172 ◽  
Author(s):  
Jacques Jedwab ◽  
Denise Badaut ◽  
Patricia Beaunier
Keyword(s):  
Clark County ◽  
Gold Mercury ◽  
Palladium Platinum

Palladium, platinum, and rhodium contents of rocks near the lower margin of the Stillwater Complex, Montana

1986 ◽  
Vol 81 (5) ◽  
pp. 1169-1178 ◽  
Author(s):  
Michael L. Zientek ◽  
Michael P. Foose ◽  
Leung Mei
Keyword(s):  
Lower Margin ◽  
Stillwater Complex ◽  
Palladium Platinum
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