Haloalkyl complexes of transition metals: preparation and characterization of (dichloromethyl)cobalt(III) derivatives

1990 ◽  
Vol 9 (8) ◽  
pp. 2177-2179 ◽  
Author(s):  
Gabriele Albertin ◽  
Stefano Antoniutti ◽  
Emilio Bordignon
Keyword(s):  
Transition Metals ◽  
Complexes Of Transition Metals

1995 Alcan Award Lecture New intermediates in the homolytic and heterolytic splitting of dihydrogen

1996 ◽  
Vol 74 (11) ◽  
pp. 1907-1915 ◽  
Author(s):  
Robert H. Morris
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Neutron Diffraction ◽  
Key Words ◽  
Research Group ◽  
Iridium Complex ◽  
Hydride Complexes ◽  
Complexes Of Transition Metals ◽  
Osmium Complexes

Some of the research of the author and his research group into the structure and reactions of dihydrogen complexes of transition metals is reviewed. The characterization of osmium complexes that can be regarded as having intermediate structures on the way to the homolytic splitting and to the heterolytic splitting of dihydrogen is described. The properties of an iridium complex with novel short proton–hydride contacts is also reviewed. Key words: transition metal, dihydrogen, hydride, complexes, NMR, neutron diffraction, osmium, iridium.

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