Synthesis of triangular mixed-metal clusters by the addition of copper electrophiles to an electron-rich rhodium-rhodium bond. X-ray crystal structures of [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-CuI)] and [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-AgO2CCH3)]
1987 ◽
Vol 6
(12)
◽
pp. 2502-2507
◽
Giuseppe. Bruno
◽
Sandra. Lo Schiavo
◽
Enrico. Rotondo
◽
Pasquale. Piraino
◽
Felice. Faraone
Stepwise addition of PtPPh3fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Ptn(µ-CO)2n(CO)10 – 2n(PPh3)n](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium–platinum mixed-metal clusters