Functional trimethylphosphine derivatives. 24. Phosphine complexes of main-group elements. 5. (Phosphinomethyl)aluminum compounds: bis- and tris(dimethylphosphino)methyl ligands in tetrahedral and octahedral aluminum phosphine complexes and x-ray structure of Al[(PMe2)2C(SiMe3)]3

Hans H. Karsch; Armin. Appelt; Juergen. Riede; Gerhard. Mueller

doi:10.1021/om00145a013

Functional trimethylphosphine derivatives. 24. Phosphine complexes of main-group elements. 5. (Phosphinomethyl)aluminum compounds: bis- and tris(dimethylphosphino)methyl ligands in tetrahedral and octahedral aluminum phosphine complexes and x-ray structure of Al[(PMe2)2C(SiMe3)]3

Organometallics ◽

10.1021/om00145a013 ◽

1987 ◽

Vol 6 (2) ◽

pp. 316-323 ◽

Cited By ~ 28

Author(s):

Hans H. Karsch ◽

Armin. Appelt ◽

Juergen. Riede ◽

Gerhard. Mueller

Keyword(s):

Main Group ◽

Main Group Elements ◽

X Ray ◽

Phosphine Complexes ◽

Aluminum Compounds

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Phosphine complexes of main group elements: phosphinomethyl substituted aluminates as anionic phosphine ligands to lithium and X-ray structure of Me2Al(CH2PMe2)2Li(Me2NCH2CH2NMe2)

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39840001415 ◽

1984 ◽

pp. 1415-1416 ◽

Cited By ~ 6

Author(s):

Hans H. Karsch ◽

Armin Appelt ◽

Gerhard Müller

Keyword(s):

Main Group ◽

Phosphine Ligands ◽

Main Group Elements ◽

X Ray ◽

Phosphine Complexes

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ChemInform Abstract: Functional Trimethylphosphine Derivatives. Part 24. Phosphine Complexes of Main Group Elements. Part 6. (Phosphinomethyl)aluminum Compounds: Bis- and Tris(dimethylphosphino)methyl Ligands in Tetrahedral and Octahedral Aluminum Phosphi

ChemInform ◽

10.1002/chin.198726238 ◽

1987 ◽

Vol 18 (26) ◽

Author(s):

H. H. KARSCH ◽

A. APPELT ◽

J. RIEDE ◽

G. MUELLER

Keyword(s):

Main Group ◽

Main Group Elements ◽

Phosphine Complexes ◽

Aluminum Compounds

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Stereochemistry of polynuclear compounds of the main group elements. Neutron and x-ray diffraction investigation of lithium-hydrogen-carbon interactions in lithium tetramethylborate

Journal of the American Chemical Society ◽

10.1021/ja00855a019 ◽

1975 ◽

Vol 97 (22) ◽

pp. 6401-6406 ◽

Cited By ~ 55

Author(s):

Wendell E. Rhine ◽

Galen Stucky ◽

S. W. Peterson

Keyword(s):

Main Group ◽

X Ray Diffraction ◽

Main Group Elements ◽

X Ray ◽

Polynuclear Compounds

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Phosphine complexes of main group elements. A bis-phosphinomethyl lithiate as an anionic diphosphine ligand to lithium: synthesis and structure of {[Me2N(CH2)2NMe2]Li[(Me2P)C(SiMe3)2]2Li}

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39870001033 ◽

1987 ◽

pp. 1033-1034 ◽

Cited By ~ 8

Author(s):

Hans H. Karsch ◽

Armin Appelt ◽

Brigitte Deubelly ◽

Gerhard Müller

Keyword(s):

Main Group ◽

Diphosphine Ligand ◽

Main Group Elements ◽

Phosphine Complexes

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ChemInform Abstract: MULTIPLE BONDS BETWEEN MAIN GROUP ELEMENTS AND TRANSITION METALS. III. SYNTHESIS, X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF μ-GERMANIUM-BIS(DICARBONYL(η5-PENTAMETHYLCYCLOPENTADIENYL)MANGANESE), μ-GE-((η5-C5ME5)MN(CO)2)2

Chemischer Informationsdienst ◽

10.1002/chin.198520278 ◽

1985 ◽

Vol 16 (20) ◽

Author(s):

J. D. KORP ◽

I. BERNAL ◽

R. HOERLEIN ◽

R. SERRANO ◽

W. A. HERRMANN

Keyword(s):

Molecular Structure ◽

Transition Metals ◽

Crystal And Molecular Structure ◽

Main Group ◽

Multiple Bonds ◽

Main Group Elements ◽

X Ray

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Stereochemical role of lone pairs in main-group elements. Part 3. Structure and bonding in trichloro(1,4,7,10,13-pentaoxacyclopentadecane)antimony(III) studied by means of X-ray crystallography at 120 K

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9870000427 ◽

1987 ◽

pp. 427 ◽

Cited By ~ 22

Author(s):

Edward Hough ◽

David G. Nicholson ◽

Asha K. Vasudevan

Keyword(s):

Main Group ◽

Main Group Elements ◽

X Ray ◽

X Ray Crystallography ◽

Lone Pairs ◽

Structure And Bonding

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Multiple bonds between transition metals and main-group elements. 73. Synthetic routes to rhenium(V) alkyl and rhenium(VII) alkylidyne complexes. X-ray crystal structures of (.eta.5-C5Me5)Re(:O) (CH3)[CH2C(CH3)3] and (.eta.5-C5Me5)(Br)3Re.tplbond.CC(CH3)3

Organometallics ◽

10.1021/om00119a013 ◽

1990 ◽

Vol 9 (5) ◽

pp. 1434-1443 ◽

Cited By ~ 12

Author(s):

Wolfgang A. Herrmann ◽

Josef K. Felixberger ◽

Reiner Anwander ◽

Eberhardt Herdtweck ◽

Paul Kiprof ◽

...

Keyword(s):

Transition Metals ◽

Crystal Structures ◽

Main Group ◽

Multiple Bonds ◽

Main Group Elements ◽

X Ray ◽

Synthetic Routes

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Phosphine complexes of main group elements: crystal structure of {Li[C(PMe2)3]-(tetrahydrofuran)}2

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39840000569 ◽

1984 ◽

pp. 569-570 ◽

Cited By ~ 14

Author(s):

Hans H. Karsch ◽

Gerhard Müller

Keyword(s):

Crystal Structure ◽

Main Group ◽

Main Group Elements ◽

Phosphine Complexes

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Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

Zeitschrift für Naturforschung B ◽

10.1515/znb-1991-0608 ◽

1991 ◽

Vol 46 (6) ◽

pp. 747-752 ◽

Cited By ~ 6

Author(s):

Wolfgang A. Herrmann ◽

Dieter W. Marz ◽

Eberhardt Herdtweck

Keyword(s):

Molecular Structure ◽

Transition Metals ◽

Single Crystal ◽

Main Group ◽

X Ray Diffraction ◽

Multiple Bonds ◽

Main Group Elements ◽

X Ray ◽

Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

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ChemInform Abstract: STEREOCHEMICAL ROLE OF LONE PAIRS IN MAIN-GROUP ELEMENTS. PART 2. STRUCTURE AND BONDING IN TRICHLORO(TETRAMETHYLTHIOUREA)ANTIMONY(III) STUDIED BY MEANS OF X-RAY CRYSTALLOGRAPHY AND ANTIMONY-121 MOESSBAUER SPECTROSCOPY

Chemischer Informationsdienst ◽

10.1002/chin.198204053 ◽

1982 ◽

Vol 13 (4) ◽

Author(s):

E. HOUGH ◽

D. G. NICHOLSON

Keyword(s):

Main Group ◽

Moessbauer Spectroscopy ◽

Main Group Elements ◽

X Ray ◽

X Ray Crystallography ◽

Lone Pairs ◽

Structure And Bonding

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