Electronic charge control of stable sites and mobilities of hydrogen atoms on a main-Group transition metal cluster surface. A comparison of [HFe4(CO)12-n(PPhMe2)nBH]PPN (n = 0-2) and HFe4(CO)12CH

1986 ◽  
Vol 5 (6) ◽  
pp. 1279-1281 ◽  
Author(s):  
Catherine E. Housecroft ◽  
Thomas P. Fehlner
Keyword(s):  
Transition Metal ◽  
Metal Cluster ◽  
Main Group ◽  
Electronic Charge ◽  
Hydrogen Atoms ◽  
Cluster Surface ◽  
Charge Control ◽  
Transition Metal Cluster

scholarly journals Coordinated “Naked” Pnicogenes and Catalysis

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 583
Author(s):  
Anna Vízi-Orosz ◽  
Gergely Berzeviczy ◽  
Gyula Pályi
Keyword(s):  
Transition Metal ◽  
Metal Cluster ◽  
Main Group ◽  
Organometallic Complexes ◽  
Present Review ◽  
Cluster Chemistry ◽  
Research Results ◽  
Transition Metal Cluster ◽  
New Type ◽  
Molecular Catalysis

Diphosphorous (P2) side-on coordinated to a dicobalt (Co–Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramifications in main-group/transition metal cluster chemistry in the last decades. The present review traces the main lines of these research results and their contacts to actual problems of industrial catalysis.

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