Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst

Pamela J. Shapiro; Emilio Bunel; William P. Schaefer; John E. Bercaw

doi:10.1021/om00117a055

Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst

Organometallics ◽

10.1021/om00117a055 ◽

1990 ◽

Vol 9 (3) ◽

pp. 867-869 ◽

Cited By ~ 336

Author(s):

Pamela J. Shapiro ◽

Emilio Bunel ◽

William P. Schaefer ◽

John E. Bercaw

Keyword(s):

Olefin Polymerization ◽

Single Component ◽

Polymerization Catalyst ◽

Alpha Olefin

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5608018 Alpha-Olefin polymerization catalyst system and process for producing alpha-olefin catalyst

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(98)80063-0 ◽

1997 ◽

Vol 125 (2-3) ◽

pp. 166-167

Author(s):

Takeshi Ebara ◽

Teruyosi Kiyota ◽

Akio Imai

Keyword(s):

Olefin Polymerization ◽

Catalyst System ◽

Polymerization Catalyst ◽

Alpha Olefin

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New NMR Spectroscopic Probe of the Absolute Stereoselectivity for Metal-Hydride and Metal-Alkyl Additions to the Carbon−Carbon Double Bond. Demonstration with a Single-Component, Isospecific Ziegler−Natta α-Olefin Polymerization Catalyst

Journal of the American Chemical Society ◽

10.1021/ja962869g ◽

1996 ◽

Vol 118 (48) ◽

pp. 12021-12028 ◽

Cited By ~ 22

Author(s):

James H. Gilchrist ◽

John E. Bercaw

Keyword(s):

Double Bond ◽

Metal Hydride ◽

Olefin Polymerization ◽

Single Component ◽

Polymerization Catalyst ◽

Carbon Double Bond ◽

The Absolute ◽

Spectroscopic Probe

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Preparation and Structural Characterization of an Enantiomerically Pure,C2-Symmetric, Single-Component Ziegler−Natta α-Olefin Polymerization Catalyst

Journal of the American Chemical Society ◽

10.1021/ja953419b ◽

1996 ◽

Vol 118 (5) ◽

pp. 1045-1053 ◽

Cited By ~ 55

Author(s):

Jonathan P. Mitchell ◽

Sharad Hajela ◽

Susan K. Brookhart ◽

Kenneth I. Hardcastle ◽

Lawrence M. Henling ◽

...

Keyword(s):

Structural Characterization ◽

Olefin Polymerization ◽

Single Component ◽

Enantiomerically Pure ◽

Polymerization Catalyst

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ChemInform Abstract: Preparation and Structural Characterization of an Enantiomerically Pure, C2-Symmetric, Single-Component Ziegler-Natta α-Olefin Polymerization Catalyst.

ChemInform ◽

10.1002/chin.199624050 ◽

2010 ◽

Vol 27 (24) ◽

pp. no-no

Author(s):

J. P. MITCHELL ◽

S. HAJELA ◽

S. K. BROOKHART ◽

K. I. HARDCASTLE ◽

L. M. HENLING ◽

...

Keyword(s):

Structural Characterization ◽

Olefin Polymerization ◽

Single Component ◽

Enantiomerically Pure ◽

Polymerization Catalyst

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Chiral, non-C2 symmetric zirconocene complexes as catalysts for stereoregular .alpha.-olefin polymerization

Journal of the American Chemical Society ◽

10.1021/ja00061a040 ◽

1993 ◽

Vol 115 (8) ◽

pp. 3326-3327 ◽

Cited By ~ 44

Author(s):

Michael A. Giardello ◽

Moris S. Eisen ◽

Charlotte L. Stern ◽

Tobin J. Marks

Keyword(s):

Olefin Polymerization ◽

Alpha Olefin

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5627117 Olefin polymerization catalyst and process for olefin polymerization

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(98)80085-x ◽

1997 ◽

Vol 125 (2-3) ◽

pp. 173

Author(s):

Teruak Mukaiyama ◽

Makoto Mitani ◽

Kunihiro Oouchi

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalyst

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130 MAO-Free new olefin polymerization catalyst systems based on FI catalysts

Science and Technology in Catalysis 2002, Proceedings of the Fourth Tokyo conference on Advance Catalytic Science and Technology - Studies in Surface Science and Catalysis ◽

10.1016/s0167-2991(03)80287-2 ◽

2003 ◽

pp. 517-518 ◽

Cited By ~ 1

Author(s):

Yasushi Nakayama ◽

Hideki Bando ◽

Hideyuki Kaneko ◽

Yoshiho Sonobe ◽

Makoto Mitani ◽

...

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalyst ◽

Catalyst Systems

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Correlation Between Catalyst Performance and Relaxation Time of Electron Donor in Olefin Polymerization Catalyst by Solid 13C NMR

KOBUNSHI RONBUNSHU ◽

10.1295/koron.2018-0023 ◽

2018 ◽

Vol 75 (6) ◽

pp. 570-575

Author(s):

Masayoshi SAITO ◽

Toshiya UOZUMI ◽

Toshihiko SUGANO ◽

Takuo KATAOKA ◽

Riichiro CHUJO

Keyword(s):

Relaxation Time ◽

Electron Donor ◽

Olefin Polymerization ◽

Polymerization Catalyst ◽

C Nmr

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Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf–C bond of a neutral pyridylamidohafnium trimethyl complex

Chemical Communications ◽

10.1039/b811384j ◽

2008 ◽

pp. 6137 ◽

Cited By ~ 33

Author(s):

Gregory J. Domski ◽

Joseph B. Edson ◽

Ivan Keresztes ◽

Emil B. Lobkovsky ◽

Geoffrey W. Coates

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalyst

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Intramolecular σ-Bond Metathesis/Protonolysis on Zirconium(IV) and Hafnium(IV) Pyridylamido Olefin Polymerization Catalyst Precursors: Exploring Unexpected Reactivity Paths

Inorganic Chemistry ◽

10.1021/ic100947q ◽

2010 ◽

Vol 49 (15) ◽

pp. 6811-6813 ◽

Cited By ~ 17

Author(s):

Lapo Luconi ◽

Giuliano Giambastiani ◽

Andrea Rossin ◽

Claudio Bianchini ◽

Agustí Lledós

Keyword(s):

Olefin Polymerization ◽

Polymerization Catalyst

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