Twelve-electron organochromium species: synthesis and characterization of high-spin square-planar chromium(II) alkyls and aryls

1988 ◽  
Vol 7 (11) ◽  
pp. 2372-2379 ◽  
Author(s):  
Ann R. Hermes ◽  
Robert J. Morris ◽  
Gregory S. Girolami
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Square Planar

Synthesis and characterization of a family of M2+ complexes supported by a trianionic ONO3− pincer-type ligand: towards the stabilization of high-spin square-planar complexes

2015 ◽  
Vol 44 (46) ◽  
pp. 20207-20215 ◽  
Author(s):  
M. E. Pascualini ◽  
S. A. Stoian ◽  
A. Ozarowski ◽  
N. V. Di Russo ◽  
A. E. Thuijs ◽  
...  
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes

A trianionic pincer-type ligand stabilizes rare Fe(ii) and Co(ii) high spin, square-planar complexes.

scholarly journals Synthesis and characterization of [7]triangulene

Nanoscale ◽  
2021 ◽  
Author(s):  
Shantanu Mishra ◽  
Kun Xu ◽  
Kristjan Eimre ◽  
Hartmut Komber ◽  
Ji Ma ◽  
...  
Keyword(s):  
High Spin ◽  
Ground States ◽  
Synthesis And Characterization ◽  
Spintronic Devices

Triangulene and its π-extended homologues constitute non-Kekulé polyradical frameworks with high-spin ground states, and are anticipated to be key components of organic spintronic devices. We report a combined in-solution and...

scholarly journals Synthesis and characterization of new complexes of Co+2 , Ni+2 , Cu+2 and Zn+2 with (Sodium acetate thio ) ethylene ligands

2013 ◽  
Vol 10 (3) ◽  
pp. 650-657
Author(s):  
Baghdad Science Journal
Keyword(s):  
Content Analysis ◽  
General Formula ◽  
Metal Content ◽  
Sodium Acetate ◽  
Magnetic Measurement ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes ◽  
Uv Visible

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .

Synthesis and Characterization of Cationic Square-Planar Iridium(I) Complexes Containing Chiral Diphosphines

1995 ◽  
Vol 14 (7) ◽  
pp. 3418-3422 ◽  
Author(s):  
Franco Morandini ◽  
Giuseppe Pilloni ◽  
Giambattista Consiglio ◽  
Antonio Mezzetti
Keyword(s):  
Synthesis And Characterization ◽  
Square Planar

Synthesis and characterization of the azido-bound five-coordinate high-spin iron(II) “picket fence” porphyrin complex

Polyhedron ◽  
2009 ◽  
Vol 28 (5) ◽  
pp. 954-958 ◽  
Author(s):  
Ibtissem Hachem ◽  
Mohamed Salah Belkhiria ◽  
Michel Giorgi ◽  
Charles E. Schulz ◽  
Habib Nasri
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Porphyrin Complex ◽  
Picket Fence ◽  
High Spin Iron

Synthesis and Characterization of Palladium(II) Complexes with Substituted Dihydrobenzoimidazoquinazoline Derivatives

2016 ◽  
Vol 15 (2) ◽  
pp. 17-32
Author(s):  
Rita Bhattacharjee
Keyword(s):  
Thermal Analysis ◽  
Biological Activity ◽  
Mass Spectra ◽  
Molar Conductivity ◽  
Synthesis And Characterization ◽  
Planar Geometry ◽  
Conductivity Measurements ◽  
Square Planar

A series of palladium(II) halo complexes of the types[PdX2L2].nH2O {n = 0, X = Cl, L = L4and L6; X = Br, L = L3,L4, L5 and L6; n = 2, X = Cl, L = L3and L7, X = Br, L = L1};Pd2X4L2 {X = Cl, Br, L = L2 and L8} and Pd2X4L3 [X = Cl, L= L1; X = Br, L = L7] were prepared where L is 6-R-5,6-dihydrobenzoimidazo quinazoline (R-Diq; where R =phenyl: L1/furyl: L2/thiophenyl: L3/o- or phydroxyphenyl: L4, L5/o- or p-chlorophenyl: L6,L7/dimethylaminophenyl: L8and characterized byelemental analyses, molar conductivity measurements,TGA, infrared, electronic, NMR and mass spectraltechniques. Based on these studies, monomeric/dimericstructure with a square planar geometry around the metalion was proposed for these complexes. Anti-microbialactivity for some of the synthesized complexes wereinvestigated.Keywords: dihydrobenzoimidazoquinazoline, palladium(II),thermal analysis, mass spectra, biological activity.

Sign in / Sign up

Export Citation Format

Share Document