Clusters containing carbene ligands. The unusual synthesis, coordination, and reactivity of a bridging (dimetalliomethyl)(diethylamino)carbene ligand in the cluster complex Os3(CO)9[.mu.3-HCC(NEt2)](.mu.-H)2

1988 ◽  
Vol 7 (10) ◽  
pp. 2241-2243 ◽  
Author(s):  
Richard D. Adams ◽  
James T. Tanner
Keyword(s):  
Cluster Complex ◽  
Carbene Ligands

Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction

2021 ◽  
Vol 70 (7) ◽  
pp. 1281-1289
Author(s):  
V. V. Chesnokov ◽  
M. A. Shevchenko ◽  
S. B. Soliev ◽  
V. A. Tafeenko ◽  
V. M. Chernyshev
Keyword(s):  
Catalytic Activity ◽  
Carbene Ligands

Cleavage of acyclic diaminocarbene ligands at an iridium(iii) center. Recognition of a new reactivity mode for carbene ligands

2019 ◽  
Vol 48 (22) ◽  
pp. 7571-7582 ◽  
Author(s):  
Mikhail A. Kinzhalov ◽  
Anzhelika A. Eremina ◽  
Andrey S. Smirnov ◽  
Vitalii V. Suslonov ◽  
Vadim Yu. Kukushkin ◽  
...  
Keyword(s):  
Carbene Ligands ◽  
Acyclic Diaminocarbene

A new reactivity mode for acyclic diaminocarbene ligands, viz. competitive cleavage of either C–NH2 or C–NHR bonds in the aminocarbene fragment, is recognized.

Ruthenium catalysts bearing N-heterocyclic carbene ligands in atom transfer radical reactions

2003 ◽  
Vol 44 (32) ◽  
pp. 6011-6015 ◽  
Author(s):  
Aurore Richel ◽  
Sébastien Delfosse ◽  
Cédric Cremasco ◽  
Lionel Delaude ◽  
Albert Demonceau ◽  
...  
Keyword(s):  
Ruthenium Catalysts ◽  
Radical Reactions ◽  
Atom Transfer ◽  
Carbene Ligands
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