Silicon in synthesis. 18. Synthesis of methyl ketones and (R)-(+)-frontalin using (1-chloro-1-(trimethylsilyl)ethyl)lithium for the direct conversion of aldehydes and ketones into .alpha.,.beta.-epoxytrimethylsilanes

Frank Cooke; Glenn Roy; Philip Magnus

doi:10.1021/om00067a001

Silicon in synthesis. 18. Synthesis of methyl ketones and (R)-(+)-frontalin using (1-chloro-1-(trimethylsilyl)ethyl)lithium for the direct conversion of aldehydes and ketones into .alpha.,.beta.-epoxytrimethylsilanes

Organometallics ◽

10.1021/om00067a001 ◽

1982 ◽

Vol 1 (7) ◽

pp. 893-897 ◽

Cited By ~ 23

Author(s):

Frank Cooke ◽

Glenn Roy ◽

Philip Magnus

Keyword(s):

Direct Conversion ◽

Methyl Ketones ◽

Aldehydes And Ketones ◽

Alpha Beta

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ChemInform Abstract: SILICON IN SYNTHESIS. 18. SYNTHESIS OF METHYL KETONES AND (R)-(+)-FRONTALIN USING (1-CHLORO-1-(TRIMETHYLSILYL)ETHYL)LITHIUM FOR THE DIRECT CONVERSION OF ALDEHYDES AND KETONES INTO α,β-EPOXYTRIMETHYLSILANES

Chemischer Informationsdienst ◽

10.1002/chin.198242259 ◽

1982 ◽

Vol 13 (42) ◽

Author(s):

F. COOKE ◽

G. ROY ◽

P. MAGNUS

Keyword(s):

Direct Conversion ◽

Methyl Ketones ◽

Aldehydes And Ketones

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ChemInform Abstract: CHEMISTRY OF OXALYL DERIVATIVES OF METHYL KETONES. XXIII. REACTION OF 5-ARYL-2,3-DIHYDROFURAN-2,3-DIONES WITH ALDEHYDES AND KETONES

Chemischer Informationsdienst ◽

10.1002/chin.198111259 ◽

1981 ◽

Vol 12 (11) ◽

Author(s):

YU. S. ANDREICHIKOV ◽

L. F. GEIN ◽

G. D. PLAKHINA

Keyword(s):

Methyl Ketones ◽

Aldehydes And Ketones ◽

Derivatives Of

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A new alkyllithium reagent for the direct conversion of aldehydes and ketones to vinylsilanes

The Journal of Organic Chemistry ◽

10.1021/jo00269a005 ◽

1989 ◽

Vol 54 (8) ◽

pp. 1784-1785 ◽

Cited By ~ 24

Author(s):

Tim F. Bates ◽

Ruthanne D. Thomas

Keyword(s):

Direct Conversion ◽

Aldehydes And Ketones

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Enamine chemistry of 2,3,4,6,7-12-hexahydroindolo[2,3-a]quinolizine. I. Reaction with .alpha.,.beta.-unsaturated aldehydes and ketones

The Journal of Organic Chemistry ◽

10.1021/jo01254a016 ◽

1969 ◽

Vol 34 (2) ◽

pp. 330-333 ◽

Cited By ~ 5

Author(s):

Robert N. Schut ◽

Frederick E. Ward ◽

Theodore J. Leipzig

Keyword(s):

Unsaturated Aldehydes ◽

Aldehydes And Ketones ◽

Alpha Beta

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ChemInform Abstract: SILICON IN SYNTHESIS - 17. CHLOROMETHYL(TRIMETHYLSILYL)LITHIUM (CHLORO(TRIMETHYLSILYL)METHYLLITHIUM) - A NEW REAGENT FOR THE DIRECT CONVERSION OF ALDEHYDES AND KETONES INTO α,β-EPOXYTRIMETHYLSILANES

Chemischer Informationsdienst ◽

10.1002/chin.198330135 ◽

1983 ◽

Vol 14 (30) ◽

Author(s):

C. BURFORD ◽

F. COOKE ◽

G. ROY ◽

P. MAGNUS

Keyword(s):

Direct Conversion ◽

Aldehydes And Ketones

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Reactions of .alpha.,.beta.-epoxysilanes with Grignard reagents. Generation and trapping of .alpha.-trimethylsilyl aldehydes and ketones

The Journal of Organic Chemistry ◽

10.1021/jo01310a035 ◽

1980 ◽

Vol 45 (22) ◽

pp. 4444-4448 ◽

Cited By ~ 33

Author(s):

Paul F. Hudrlik ◽

Anne M. Hudrlik ◽

Raj N. Misra ◽

David Peterson ◽

Gregory P. Withers ◽

...

Keyword(s):

Grignard Reagents ◽

Aldehydes And Ketones ◽

Alpha Beta

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Ozonolysis in Solvent/Water Mixtures: Direct Conversion of Alkenes to Aldehydes and Ketones

The Journal of Organic Chemistry ◽

10.1021/jo800323x ◽

2008 ◽

Vol 73 (12) ◽

pp. 4688-4690 ◽

Cited By ~ 66

Author(s):

Charles E. Schiaffo ◽

Patrick H. Dussault

Keyword(s):

Direct Conversion ◽

Solvent Water ◽

Aldehydes And Ketones

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Selective reductions. 22. Facile reduction of .alpha.,.beta.-unsaturated aldehydes and ketones with 9-borabicyclo[3.3.1]nonane. A remarkably convenient procedure for the selective conversion of conjugated aldehydes and ketones to the corresponding allylic alcohols in the presence of other functional groups

The Journal of Organic Chemistry ◽

10.1021/jo00427a021 ◽

1977 ◽

Vol 42 (7) ◽

pp. 1197-1201 ◽

Cited By ~ 60

Author(s):

S. Krishnamurthy ◽

Herbert C. Brown

Keyword(s):

Functional Groups ◽

Allylic Alcohols ◽

Convenient Procedure ◽

Unsaturated Aldehydes ◽

Selective Conversion ◽

Aldehydes And Ketones ◽

Alpha Beta

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Direct Conversion of Heteroaromatic Esters to Methyl Ketones with Trimethylaluminum: Nonsymmetrically Disubstituted 1,2,4,5-Tetrazines

The Journal of Organic Chemistry ◽

10.1021/jo9815352 ◽

1998 ◽

Vol 63 (26) ◽

pp. 10063-10068 ◽

Cited By ~ 30

Author(s):

Marc Girardot ◽

Rana Nomak ◽

John K. Snyder

Keyword(s):

Direct Conversion ◽

Methyl Ketones

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Direct Conversion of Aldehydes and Ketones to Allylic Halides by a NbX5-[3,3] Rearrangement

Synlett ◽

10.1055/s-0028-1088222 ◽

2009 ◽

Vol 2009 (07) ◽

pp. 1077-1080 ◽

Cited By ~ 13

Author(s):

Fraser Fleming ◽

P. Ravikumar ◽

Lihua Yao

Keyword(s):

Direct Conversion ◽

Aldehydes And Ketones ◽

Allylic Halides

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