Hydrogenation of the central carbon-carbon bond of coordinated .alpha.-diimine ligands of H2Ru2(CO)5(iso-PrN:C(H)C(R):Niso-Pr) (R = hydrogen, methyl), involving carbon-hydrogen and ruthenium-hydrogen bond-making and -breaking processes

1992 ◽  
Vol 11 (12) ◽  
pp. 4250-4260 ◽  
Author(s):  
Marco J. A. Kraakman ◽  
Cornelis J. Elsevier ◽  
Kees Vrieze ◽  
Anthony L. Spek
Keyword(s):  
Hydrogen Bond ◽  
Carbon Bond ◽  
Diimine Ligands ◽  
Carbon Carbon Bond ◽  
Central Carbon

The reaction of Sodium Acetylide with Benzil and related compounds

1956 ◽  
Vol 9 (3) ◽  
pp. 391 ◽  
Author(s):  
J Cymerman-Craig ◽  
M Moyle ◽  
P Rowe-Smith ◽  
PC Wailes
Keyword(s):  
Liquid Ammonia ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Central Carbon ◽  
Related Compounds

Attempted condensation of benzil and benzoin with sodium acetylide in liquid ammonia caused fission of the central carbon-carbon bond of these substances, giving 3-phenylprop-1-yn-3-ol. Condensation of α-bromodeoxyanisoin with the same reagent gave several non-acetylenic products which have been identified.

Facile Carbon–Carbon Bond Formation and Multiple Carbon–Hydrogen Bond Activations Promoted by Methylene-Bridged Iridium/Ruthenium Complexes

2011 ◽  
Vol 30 (21) ◽  
pp. 5882-5893 ◽  
Author(s):  
Tiffany J. MacDougall ◽  
Steven J. Trepanier ◽  
Jason L. Dutton ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Formation ◽  
Ruthenium Complexes ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Bond Activations
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