Cluster synthesis. 40. New high-nuclearity platinum-ruthenium carbonyl cluster complexes. Synthesis and structural characterizations of Ru8Pt2(CO)23(.mu.3-H)2, Ru7Pt3(CO)22(.mu.3-H)2, and Ru8Pt2(CO)21(.mu.3-.eta.2-CO)2(dppe)(.mu.-H)2 with a new type of triply bridging CO ligand and a new layered cluster complex Ru6Pt3(CO)21(.mu.-CO)(.mu.3-H)2

1992 ◽  
Vol 11 (12) ◽  
pp. 4001-4009 ◽  
Author(s):  
Richard D. Adams ◽  
Zhaoyang Li ◽  
Jau Ching Lii ◽  
Wengan Wu
Keyword(s):  
Cluster Complex ◽  
Carbonyl Cluster ◽  
Cluster Complexes ◽  
Ruthenium Carbonyl ◽  
New Type ◽  
Structural Characterizations

Platinum-ruthenium Carbonyl Cluster Complexes

2007 ◽  
pp. 280-284 ◽  
Author(s):  
R. D. Adams ◽  
T. S. Barnard ◽  
J. E. Cortopassi ◽  
W. Wu ◽  
Z. Li ◽  
...  
Keyword(s):  
Carbonyl Cluster ◽  
Cluster Complexes ◽  
Ruthenium Carbonyl

Synthesis and Characterization of a New Type of Highnuclear Lanthanide – Cobalt Carboxylate Cluster Complex

2014 ◽  
Vol 908 ◽  
pp. 42-45
Author(s):  
Oyun Erdene Byambasuren ◽  
Feng Hua Bai ◽  
Yin Xia Zhang ◽  
Hai Quan Su
Keyword(s):  
Cluster Structure ◽  
Cluster Complex ◽  
Carbonyl Cluster ◽  
X Ray Diffraction ◽  
Monoclinic Crystal ◽  
X Ray ◽  
Heterometallic Cluster ◽  
Carboxylate Groups ◽  
Rare Class ◽  
New Type

A new heteronuclear Ln-Co carbonyl cluster, Ce4Yb2(μ3-L)4(CF3COO)8(DMF)6Co (L=(CO)6Co2CC(COO)2-), has been synthesized by reaction of (CO)6Co2CC(COOH)2 with Ce (OOCCF3)32H2O and Yb (OOCCF3)32H2O. The cluster structure was characterized by single-crystal X-ray diffraction and IR. The crystal is monoclinic crystal system and C2/c space group. X-ray analysis revealed that the heterometallic cluster belonged to a rare class of Ln-Co carbonyl cluster bridged by carboxylate groups of carbonyl cluster ligands. The cluster was monometric unit and exhibited cage-like configuration.

Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton:  Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms

2006 ◽  
Vol 25 (23) ◽  
pp. 5672-5675 ◽  
Author(s):  
Javier A. Cabeza ◽  
Ignacio del Río ◽  
Pablo García-Álvarez ◽  
Daniel Miguel
Keyword(s):  
Pentagonal Bipyramid ◽  
Carbonyl Cluster ◽  
Cluster Complexes ◽  
Metal Atoms ◽  
Ruthenium Carbonyl
Sign in / Sign up

Export Citation Format

Share Document