Unusual .eta.6-toluene coordination to an alkali metal. X-ray crystal structure of organolutetium complex Lu{CH(SiMe3)2}3(.mu.-Cl)K(.eta.6-C7H8)2 and the solubilization of unsolvated alkali-metal halides in hydrocarbon media

1991 ◽  
Vol 10 (6) ◽  
pp. 1704-1709 ◽  
Author(s):  
Colin J. Schaverien ◽  
Jan B. Van Mechelen
Keyword(s):  
Crystal Structure ◽  
Alkali Metal ◽  
Metal Halides ◽  
X Ray ◽  
Alkali Metal Halides ◽  
Hydrocarbon Media

Satellite structure in the x-ray photoelectron spectra of rare gases and alkali-metal halides

1974 ◽  
Vol 9 (4) ◽  
pp. 1603-1611 ◽  
Author(s):  
David P. Spears ◽  
Helmut J. Fischbeck ◽  
Thomas A. Carlson
Keyword(s):  
Alkali Metal ◽  
Photoelectron Spectra ◽  
Rare Gases ◽  
Metal Halides ◽  
Satellite Structure ◽  
X Ray ◽  
Alkali Metal Halides

A Novel Alkali-Metal Hydrido-tris(pyrazolyl)borate (Tp*) Complex. Isolation and Crystal Structure of [(Me2CO)3(NaTp*)2]

2014 ◽  
Vol 69 (7) ◽  
pp. 793-798
Author(s):  
Laurent Plasseraud ◽  
Hélène Cattey
Keyword(s):  
Crystal Structure ◽  
Alkali Metal ◽  
Sodium Hydroxide ◽  
Title Compound ◽  
Room Temperature ◽  
Crystallographic Analysis ◽  
Monoclinic Space Group ◽  
Large Excess ◽  
X Ray ◽  
Acetone Water

The title compound was isolated from the treatment of Tp*Sn(Cl)2Bu (1) with a large excess of sodium hydroxide in a mixture of acetone-water at room temperature. [(Me2CO)3(NaTp*)2] (2) crystallizes at 4 °C as prismatic colorless crystals, in the monoclinic space group P21/c with Z = 4, a = 12.2837(6), b = 24.3197(12), c = 16.9547(8) Å, β = 110.017(1)°, and V = 4759.0(4) Å3. The X-ray crystallographic analysis revealed a dinuclear unit in which two Tp*Na moieties are held together by three bridging acetone molecules acting as oxygen-based donors.

scholarly journals Environmentally Benign Electrophilic Halogenation of Naphthalenes by H<sub>2</sub>O<sub>2</sub>—Alkali Metal Halides in An Aqueous Cationic Micellar Media

2012 ◽  
Vol 02 (03) ◽  
pp. 254-261 ◽  
Author(s):  
Kancharla Rajendar Reddy ◽  
Sariah Sana ◽  
Kusampally Uppalaiah ◽  
Kamatala Chinna Rajanna ◽  
Puppala Veerasomaiah
Keyword(s):  
Alkali Metal ◽  
Environmentally Benign ◽  
Micellar Media ◽  
Metal Halides ◽  
Alkali Metal Halides
Sign in / Sign up

Export Citation Format

Share Document