Thermal chemistry of molybdenum complex CpMo(NO)(CH2CMe3)2: Lewis base adducts of CpMo(NO)(:CHCMe3) and a new bonding mode for nitric oxide

1993 ◽  
Vol 12 (9) ◽  
pp. 3575-3585 ◽  
Author(s):  
Peter Legzdins ◽  
Steven J. Rettig ◽  
John E. Veltheer ◽  
Raymond J. Batchelor ◽  
Frederick W. B. Einstein
Keyword(s):  
Nitric Oxide ◽  
Lewis Base ◽  
Molybdenum Complex ◽  
Thermal Chemistry ◽  
Bonding Mode

Thermal Chemistry of Cp*W(NO)(CH2CMe3)(H)(L) Complexes (L = Lewis Base)

2016 ◽  
Vol 56 (1) ◽  
pp. 573-582 ◽  
Author(s):  
Diana Fabulyak ◽  
Rex C. Handford ◽  
Aaron S. Holmes ◽  
Taleah M. Levesque ◽  
Russell J. Wakeham ◽  
...  
Keyword(s):  
Lewis Base ◽  
Thermal Chemistry

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

2014 ◽  
Vol 43 (44) ◽  
pp. 16610-16613 ◽  
Author(s):  
Takako Muraoka ◽  
Keisuke Abe ◽  
Haruhiko Kimura ◽  
Youhei Haga ◽  
Keiji Ueno ◽  
...  
Keyword(s):  
Lewis Base ◽  
Molybdenum Complex ◽  
Molybdenum Complexes

Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the MSi bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L.

Frustrated Lewis pairs: Some recent developments

2012 ◽  
Vol 84 (11) ◽  
pp. 2203-2217 ◽  
Author(s):  
Gerhard Erker
Keyword(s):  
Nitric Oxide ◽  
Lewis Acid ◽  
Lewis Base ◽  
Frustrated Lewis Pairs ◽  
Recent Developments ◽  
New Type ◽  
Lewis Pairs

The chemistry of some reactive frustrated Lewis pairs (FLPs) is reported. This includes intramolecular P/B and N/B FLPs, some of which were used as catalysts for the hydrogenation of electron-rich olefin substrates. Some advanced intermolecular FLPs are reported, which includes systems derived from very bulky alkenyl boranes obtained from 1,1-carboboration reactions of 1-alkynes with tris(pentafluorophenyl)borane. Some such systems activate dihydrogen and transfer the resulting proton/hydride pair even to some electron-poor alkynes. Eventually, we report on the reaction of our intramolecular ethylene-bridged P/B FLP with nitric oxide (NO). N,B-addition of the P-Lewis base/B-Lewis acid combination is observed to form a new type of a persistent aminoxyl radical. Some of the chemistry of the new FLP-NO radicals is presented and discussed.

Localization of endothelial nitric oxide synthase in the normal and failing human atrial myocardium

1996 ◽  
Vol 54 ◽  
pp. 786-787
Author(s):  
Chi-Ming Wei ◽  
Margarita Bracamonte ◽  
Shi-Wen Jiang ◽  
Richard C. Daly ◽  
Christopher G.A. McGregor ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Heart Failure ◽  
Nitric Oxide Synthase ◽  
Endothelial Nitric Oxide Synthase ◽  
Cardiac Tissues ◽  
Mammalian Tissues ◽  
End Stage Heart Failure ◽  
End Stage ◽  
Oxide Synthase ◽  
Endothelial Nitric Oxide

Nitric oxide (NO) is a potent endothelium-derived relaxing factor which also may modulate cardiomyocyte inotropism and growth via increasing cGMP. While endothelial nitric oxide synthase (eNOS) isoforms have been detected in non-human mammalian tissues, expression and localization of eNOS in the normal and failing human myocardium are poorly defined. Therefore, the present study was designed to investigate eNOS in human cardiac tissues in the presence and absence of congestive heart failure (CHF).Normal and failing atrial tissue were obtained from six cardiac donors and six end-stage heart failure patients undergoing primary cardiac transplantation. ENOS protein expression and localization was investigated utilizing Western blot analysis and immunohistochemical staining with the polyclonal rabbit antibody to eNOS (Transduction Laboratories, Lexington, Kentucky).

Nitric Oxide Reduces Pressor Responsiveness During Ovine Hypoadrenocorticism

2001 ◽  
Vol 28 (5-6) ◽  
pp. 459-462
Author(s):  
Pini Orbach ◽  
Charles E Wood ◽  
Maureen Keller-Wood
Keyword(s):  
Nitric Oxide

Nitric oxide synthase and cellac disease

2001 ◽  
Vol 120 (5) ◽  
pp. A684-A684
Author(s):  
I DANIELS ◽  
I MURRAY ◽  
W GODDARD ◽  
R LONG
Keyword(s):  
Nitric Oxide ◽  
Nitric Oxide Synthase ◽  
Oxide Synthase
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