Synthesis and Characterization of Palladium Complexes Containing Tridentate Ligands with PXP (X = C, N, O, S, As) Donor Sets and Their Evaluation as Electrochemical CO2 Reduction Catalysts

1994 ◽  
Vol 13 (12) ◽  
pp. 4844-4855 ◽  
Author(s):  
Bryan D. Steffey ◽  
Alex Miedaner ◽  
Mary L. Maciejewski-Farmer ◽  
Paul R. Bernatis ◽  
Andrew M. Herring ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Tridentate Ligands ◽  
Electrochemical Co2 Reduction ◽  
Reduction Catalysts

Synthesis and Characterization of Silver and Palladium Complexes with Xanthene-Based N-Heterocyclic Carbene−Oxazoline Ligands

2010 ◽  
Vol 29 (23) ◽  
pp. 6291-6297 ◽  
Author(s):  
Takeshi Makino ◽  
Ryu Yamasaki ◽  
Isao Azumaya ◽  
Hyuma Masu ◽  
Shinichi Saito
Keyword(s):  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Oxazoline Ligands

Synthesis and Characterization of Novel PEPPSI type Pd–BICAAC Complexes

2022 ◽  
Author(s):  
Márton Nagyházi ◽  
Balázs Almási ◽  
Ádám Lukács ◽  
Attila Bényei ◽  
Tibor Nagy ◽  
...  
Keyword(s):  
High Activity ◽  
Coupling Reaction ◽  
Kinetic Studies ◽  
Elemental Mercury ◽  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Heck Coupling ◽  
Moisture Resistant

A series of bicyclic alkylamino carbenes (BICAAC) (where N-aryl = dipp, mes, 2,6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, 4 dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes (6a-e) were synthetized and characterized. The new palladium complexes have shown high activity in Mizoroki–Heck coupling reaction even at as low as 100 ppm loading (TON up to 10000). Kinetic studies revealed that reactions carried out in the presence of elemental mercury resulted in decrease in activity. It indicates that the coupling reaction may have both molecular and Pd(0)-mediated catalytic paths.

Synthesis and characterization of new galactosylated-based N2O-donors tridentate ligands

2019 ◽  
Vol 49 (10) ◽  
pp. 1316-1324
Author(s):  
Lidiane C. Castro ◽  
Yasmim R. Jaconiano ◽  
Tereza C. S. Evangelista ◽  
Sabrina B. Ferreira ◽  
Marciela Scarpellini
Keyword(s):  
Synthesis And Characterization ◽  
Tridentate Ligands

Synthesis and characterization of Zn2GeO4/Mg-MOF-74 composites with enhanced photocatalytic activity for CO2 reduction

2018 ◽  
Vol 8 (5) ◽  
pp. 1288-1295 ◽  
Author(s):  
Hui Zhao ◽  
Xusheng Wang ◽  
Jifei Feng ◽  
Yanning Chen ◽  
Xue Yang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Co2 Reduction ◽  
Synthesis And Characterization ◽  
Mild Conditions

Zn2GeO4/Mg-MOF-74 composites are explored for artificial CO2 phototransformation under mild conditions.

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