Synthesis, Characterization, and Structural Investigation of the First Bioinorganic Titanocene(IV) .alpha.-Amino Acid Complexes Prepared from the Antitumor Agent Titanocene Dichloride

Thomas M. Klapoetke; Hartmut Koepf; Inis C. Tornieporth-Oetting; Peter S. White

doi:10.1021/om00021a040

Synthesis, Characterization, and Structural Investigation of the First Bioinorganic Titanocene(IV) .alpha.-Amino Acid Complexes Prepared from the Antitumor Agent Titanocene Dichloride

Organometallics ◽

10.1021/om00021a040 ◽

1994 ◽

Vol 13 (9) ◽

pp. 3628-3633 ◽

Cited By ~ 51

Author(s):

Thomas M. Klapoetke ◽

Hartmut Koepf ◽

Inis C. Tornieporth-Oetting ◽

Peter S. White

Keyword(s):

Amino Acid ◽

Structural Investigation ◽

Antitumor Agent ◽

Titanocene Dichloride ◽

Amino Acid Complexes ◽

Alpha Amino Acid

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Ionic Titanocene(IV) .alpha.-Amino Acid Complexes of DL-Phenylalanine and DL-4-Fluorophenylalanine: Synthesis, Characterization, and Investigation of the Antimicrobial Behavior toward Escherichia coli

Organometallics ◽

10.1021/om00004a017 ◽

1995 ◽

Vol 14 (4) ◽

pp. 1632-1636 ◽

Cited By ~ 30

Author(s):

Inis C. Tornieporth-Oetting ◽

Peter S. White

Keyword(s):

Escherichia Coli ◽

Amino Acid ◽

Amino Acid Complexes ◽

Alpha Amino Acid

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Asymmetric epoxidation of allylic alcohols catalyzed by titanium alkoxide-peptide and -.alpha.-amino acid complexes anchored by phenolic Schiff base.

The Journal of Organic Chemistry ◽

10.1021/jo00049a050 ◽

1992 ◽

Vol 57 (23) ◽

pp. 6329-6331 ◽

Cited By ~ 11

Author(s):

Yuki Iseki ◽

Masanobu Kudo ◽

Atsunori Mori ◽

Shohei Inoue

Keyword(s):

Schiff Base ◽

Amino Acid ◽

Asymmetric Epoxidation ◽

Allylic Alcohols ◽

Titanium Alkoxide ◽

Amino Acid Complexes ◽

Alpha Amino Acid

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Preparation of N-carboxy-.alpha.-amino acid anhydrides by the reaction of copper(II)-amino acid complexes with phosgene

The Journal of Organic Chemistry ◽

10.1021/jo00838a059 ◽

1969 ◽

Vol 34 (1) ◽

pp. 243-244 ◽

Cited By ~ 2

Author(s):

Rodney D. Hamilton ◽

Donald J. Lyman

Keyword(s):

Amino Acid ◽

Amino Acid Complexes ◽

Acid Anhydrides ◽

Alpha Amino Acid

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Iron(II)-.alpha.-Amino Acid Complexes from Nonprotic Solutions: Reactions of [Fe(Mes)2(phen)] with .alpha.-Amino Acids and the Structures of Bis(L-Prolinato)(1,10-phenanthroline)iron(II) and Bis(D-prolinato)(1,10-phenanthroline)iron(II)

Inorganic Chemistry ◽

10.1021/ic00087a032 ◽

1994 ◽

Vol 33 (9) ◽

pp. 1928-1933 ◽

Cited By ~ 8

Author(s):

C. Philippe Magill ◽

Carlo Floriani ◽

Angiola Chiesi-Villa ◽

Corrado Rizzoli

Keyword(s):

Amino Acids ◽

Amino Acid ◽

Amino Acid Complexes ◽

Alpha Amino Acid

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Faculty Opinions recommendation of Catalytic enantio- and diastereoselective aldol reactions of glycine-derived silicon enolate with aldehydes: an efficient approach to the asymmetric synthesis of anti-beta-hydroxy-alpha-amino acid derivatives.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1020519.232639 ◽

2004 ◽

Author(s):

Carlos F Barbas

Keyword(s):

Amino Acid ◽

Asymmetric Synthesis ◽

Aldol Reactions ◽

Amino Acid Derivatives ◽

Efficient Approach ◽

Alpha Amino Acid

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Faculty Opinions recommendation of Deorphanization of GPRC6A: a promiscuous L-alpha-amino acid receptor with preference for basic amino acids.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1024356.287883 ◽

2005 ◽

Author(s):

Joseph Heitman

Keyword(s):

Amino Acids ◽

Amino Acid ◽

Acid Receptor ◽

Basic Amino Acids ◽

Alpha Amino Acid

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Potentiometric study of enantioselective effects in α-amino acid complexes of copper(II)

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)83787-1 ◽

1985 ◽

Vol 104 (1) ◽

pp. 63-67 ◽

Cited By ~ 6

Author(s):

I.L. Ulanovski ◽

A.A. Kurganov ◽

V.A. Davankov

Keyword(s):

Amino Acid ◽

Potentiometric Study ◽

Amino Acid Complexes

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Alkali-metal hexamethyldisilazide initiated polymerization on alpha-amino acid N-substituted N-carboxyanhydrides for facile polypeptoid synthesis

Chinese Chemical Letters ◽

10.1016/j.cclet.2021.02.039 ◽

2021 ◽

Author(s):

Yueming Wu ◽

Min Zhou ◽

Kang Chen ◽

Sheng Chen ◽

Ximian Xiao ◽

...

Keyword(s):

Amino Acid ◽

Alkali Metal ◽

Alpha Amino Acid

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Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes

Molecules ◽

10.3390/molecules26144331 ◽

2021 ◽

Vol 26 (14) ◽

pp. 4331

Author(s):

David B. Hobart ◽

Michael A. G. Berg ◽

Hannah M. Rogers ◽

Joseph S. Merola

Keyword(s):

Amino Acid ◽

High Resolution Mass Spectrometry ◽

Resonance Spectroscopy ◽

Spectroscopic Techniques ◽

X Ray Diffraction ◽

Amino Acid Complexes ◽

Acetone Water ◽

Square Planar ◽

Non Covalent Interactions ◽

Covalent Interactions

The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectroscopic techniques, especially HRMS (high resolution mass spectrometry), IR (infrared spectroscopy), and 1H NMR (nuclear magnetic resonance) spectroscopy. In some cases, suitable crystals for single crystal X-ray diffraction were able to be grown and the molecular structure was obtained. The molecular geometries of the products are discussed. Except for the alanine complex, all complexes incorporate water molecules into the extended lattice and exhibit N-H···O and/or O···(HOH)···O hydrogen bonding interactions. The non-covalent interactions are discussed in terms of the extended lattice structures exhibited by the structures.

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