Synthesis, Molecular Structure, and Reactivity of a Half-Sandwich Vanadium(III) Imido Complex: The First Vanadium(V) Alkylidene

Jan-Karel F. Buijink; Jan H. Teuben; Huub Kooijman; Anthony L. Spek

doi:10.1021/om00020a003

Synthesis, Molecular Structure, and Reactivity of a Half-Sandwich Vanadium(III) Imido Complex: The First Vanadium(V) Alkylidene

Organometallics ◽

10.1021/om00020a003 ◽

1994 ◽

Vol 13 (8) ◽

pp. 2922-2924 ◽

Cited By ~ 60

Author(s):

Jan-Karel F. Buijink ◽

Jan H. Teuben ◽

Huub Kooijman ◽

Anthony L. Spek

Keyword(s):

Molecular Structure ◽

Half Sandwich

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Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles

Materials ◽

10.3390/ma6115352 ◽

2013 ◽

Vol 6 (11) ◽

pp. 5352-5366 ◽

Cited By ~ 16

Author(s):

Gajendra Gupta ◽

Benjamin Murray ◽

Paul Dyson ◽

Bruno Therrien

Keyword(s):

Molecular Structure ◽

Water Soluble ◽

Molecular Materials ◽

Half Sandwich

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Molecular Structure of 113C-C2H4/C3H6 Copolymers Prepared in the Presence of Half Sandwich Titanium Methyl - B(C6F5)3 Catalysts

Macromolecular Chemistry and Physics ◽

10.1002/macp.200500342 ◽

2005 ◽

Vol 206 (23) ◽

pp. 2342-2347 ◽

Cited By ~ 2

Author(s):

Irene Sessa ◽

Zsolt Csok ◽

Adolfo Zambelli

Keyword(s):

Molecular Structure ◽

Half Sandwich

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The use of half-sandwich iridium dithiolate and diselenolate complexes, CpIr(L)(ER)2 (L=CO, PMe3, PPh3; ER=SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of CpIr(CO)(μ-SePh)2[Mo(CO)4]

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(98)00739-6 ◽

1998 ◽

Vol 570 (2) ◽

pp. 241-246 ◽

Cited By ~ 12

Author(s):

Max Herberhold ◽

Guo-Xin Jin ◽

Arnold L. Rheingold

Keyword(s):

Molecular Structure ◽

Half Sandwich

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Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9

Zeitschrift für Naturforschung B ◽

10.1515/znb-1981-0901 ◽

1981 ◽

Vol 36 (9) ◽

pp. 1053-1059 ◽

Cited By ~ 9

Author(s):

Ernst Guggolz ◽

Manfred L. Ziegler ◽

Willibald Kalcher ◽

Johann Plank ◽

Doris Riedel ◽

...

Keyword(s):

Molecular Structure ◽

Cluster Compound ◽

The Novel ◽

X Ray Diffraction ◽

Sandwich Complex ◽

X Ray ◽

Trinuclear Cluster ◽

Half Sandwich

Abstract Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(η5 -C5Me5)Ir(μ-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (η5 -C5Me5)IrFe2(CO)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (η5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8.

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Synthesis and molecular structure of hetero-metallic cluster CpCoW(CO)2(S2C2B10H10)2 and binuclear half-sandwich Co complex [Cp∗Co(S2C2B10H10)]2(bpo) with dichalcogenolate o-carboranyl ligands

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2007.11.013 ◽

2008 ◽

Vol 11 (2) ◽

pp. 145-149 ◽

Cited By ~ 12

Author(s):

Jia-Sheng Zhang ◽

Guo-Xin Jin

Keyword(s):

Molecular Structure ◽

Metallic Cluster ◽

Half Sandwich

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Different structural features of half-sandwich complexes of rhodium(I) containing the η5-1,2,4-triphosphacyclopentadienyl ring. Syntheses and31P n.m.r. spectra of [Rh(η5-C2R2P3)LL′][R = But, L = L′= PPh3,P(p-tolyl)3; L = CO, L′= PPh3; LL′= cyclo-octa-1,5-diene; R = adamantyl, L = PMe3,PPh3]; crystal and molecular structure of [Rh(η5-C2But2P3)(η4-C8H12)]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39880001475 ◽

1988 ◽

pp. 1475-1476 ◽

Cited By ~ 13

Author(s):

Rainer Bartsch ◽

Peter B. Hitchcock ◽

Timothy J. Madden ◽

Mohamed F. Meidine ◽

John F. Nixon ◽

...

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Structural Features ◽

Sandwich Complexes ◽

Half Sandwich

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Synthesis and molecular structure of half-sandwich ruthenium(II) complexes containing pyrazolyl ligands: Solvent induced geometrical change in κ2-scorpionate supported complex

Journal of Molecular Structure ◽

10.1016/j.molstruc.2021.132005 ◽

2021 ◽

pp. 132005

Author(s):

G. Reshma ◽

S. Nakul ◽

P.M. Mahitha ◽

Naveen V. Kulkarni ◽

Dineshchakravarthy Senthurpandi ◽

...

Keyword(s):

Molecular Structure ◽

Geometrical Change ◽

Half Sandwich

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Structure and reactivity of ruthenium half-sandwich compounds: crystal and molecular structure and acetonitrile exchange kinetics and mechanism of tris(acetonitrile)(.eta.6-benzene)ruthenium(2+) and tris(acetonitrile)(.eta.5-cyclopentadienyl)ruthenium(+)

Inorganic Chemistry ◽

10.1021/ic00010a024 ◽

1991 ◽

Vol 30 (10) ◽

pp. 2350-2355 ◽

Cited By ~ 60

Author(s):

Werner. Luginbuehl ◽

Pascal. Zbinden ◽

Pierre A. Pittet ◽

Thomas. Armbruster ◽

Hans Beat. Buergi ◽

...

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Kinetics And Mechanism ◽

Sandwich Compounds ◽

Exchange Kinetics ◽

Half Sandwich

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Half-sandwich molybdenum complexes: molecular structure and catalyst precursors for olefin epoxidation with tert-butyl hydroperoxide

Mendeleev Communications ◽

10.1016/j.mencom.2018.09.019 ◽

2018 ◽

Vol 28 (5) ◽

pp. 508-510 ◽

Cited By ~ 3

Author(s):

Mikhail E. Minyaev ◽

Alexander A. Vinogradov ◽

Andrei V. Churakov ◽

Barbara Kimmich ◽

Ilya E. Nifant’ev ◽

...

Keyword(s):

Molecular Structure ◽

Olefin Epoxidation ◽

Molybdenum Complexes ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide ◽

Half Sandwich

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The synthesis of half-sandwich bis(pentafluorophenyl)boryl-substituted cyclopentadienyl zirconium, niobium and tantalum complexes and the isolation and molecular structure of a zwitterionic niobocene

Dalton Transactions ◽

10.1039/b300552f ◽

2003 ◽

pp. 1779-1789 ◽

Cited By ~ 17

Author(s):

Simon J. Lancaster ◽

David L. Hughes

Keyword(s):

Molecular Structure ◽

Half Sandwich

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Synthesis, Molecular Structure, and Reactivity of a Half-Sandwich Vanadium(III) Imido Complex: The First Vanadium(V) Alkylidene

Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles

Molecular Structure of 113C-C2H4/C3H6 Copolymers Prepared in the Presence of Half Sandwich Titanium Methyl - B(C6F5)3 Catalysts

The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)2 (L=CO, PMe3, PPh3; ER=SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(μ-SePh)2[Mo(CO)4]

Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9

Synthesis and molecular structure of hetero-metallic cluster CpCoW(CO)2(S2C2B10H10)2 and binuclear half-sandwich Co complex [Cp∗Co(S2C2B10H10)]2(bpo) with dichalcogenolate o-carboranyl ligands

Synthesis and molecular structure of half-sandwich ruthenium(II) complexes containing pyrazolyl ligands: Solvent induced geometrical change in κ2-scorpionate supported complex

Structure and reactivity of ruthenium half-sandwich compounds: crystal and molecular structure and acetonitrile exchange kinetics and mechanism of tris(acetonitrile)(.eta.6-benzene)ruthenium(2+) and tris(acetonitrile)(.eta.5-cyclopentadienyl)ruthenium(+)

Half-sandwich molybdenum complexes: molecular structure and catalyst precursors for olefin epoxidation with tert-butyl hydroperoxide

The synthesis of half-sandwich bis(pentafluorophenyl)boryl-substituted cyclopentadienyl zirconium, niobium and tantalum complexes and the isolation and molecular structure of a zwitterionic niobocene

The use of half-sandwich iridium dithiolate and diselenolate complexes, CpIr(L)(ER)2 (L=CO, PMe3, PPh3; ER=SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of CpIr(CO)(μ-SePh)2[Mo(CO)4]