Double-Dimethylsilyl-Bridged Dicyclopentadienyl Group 4 Metal Complexes. X-ray Molecular Structures of M[(Me2Si)2(.eta.5-C5H3)2]Cl2 (M = Ti, Zr) and (TiCl3)2{.mu.-[(Me2Si)2(.eta.5-C5H3)2]}

Ana Cano; Tomas Cuenca; Pilar Gomez-Sal; Beatriz Royo; Pascual Royo

doi:10.1021/om00017a028

Double-Dimethylsilyl-Bridged Dicyclopentadienyl Group 4 Metal Complexes. X-ray Molecular Structures of M[(Me2Si)2(.eta.5-C5H3)2]Cl2 (M = Ti, Zr) and (TiCl3)2{.mu.-[(Me2Si)2(.eta.5-C5H3)2]}

Organometallics ◽

10.1021/om00017a028 ◽

1994 ◽

Vol 13 (5) ◽

pp. 1688-1694 ◽

Cited By ~ 42

Author(s):

Ana Cano ◽

Tomas Cuenca ◽

Pilar Gomez-Sal ◽

Beatriz Royo ◽

Pascual Royo

Keyword(s):

Metal Complexes ◽

Molecular Structures ◽

X Ray ◽

Group 4 ◽

Group 4 Metal

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Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {CpHfCl2[Ph4P2N3(NH)S2]}2, CpZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl

Inorganic Chemistry ◽

10.1021/ic00111a012 ◽

1995 ◽

Vol 34 (7) ◽

pp. 1681-1687 ◽

Cited By ~ 3

Author(s):

Tristram Chivers ◽

Xiaoliang Gao ◽

Masood Parvez

Keyword(s):

Metal Complexes ◽

X Ray ◽

Group 4 ◽

Group 4 Metal

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Molecular structures of the main group 4 metal(II) bis(trimethylsilyl)-amides M[N(SiMe3)2]2 in the crystal (X-ray) and vapour (gas-phase electron diffraction)

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39830000639 ◽

1983 ◽

pp. 639 ◽

Cited By ~ 106

Author(s):

Torgny Fjeldberg ◽

H�kon Hope ◽

Michael F. Lappert ◽

Philip P. Power ◽

Andrew J. Thorne

Keyword(s):

Electron Diffraction ◽

Gas Phase ◽

Main Group ◽

Molecular Structures ◽

X Ray ◽

Group 4 ◽

Group 4 Metal ◽

Gas Phase Electron Diffraction

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Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [CpZrCl3(2-TCMP)], Cp=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(01)00815-4 ◽

2001 ◽

Vol 629 (1-2) ◽

pp. 68-76 ◽

Cited By ~ 1

Author(s):

A. Otero ◽

J. Fernández-Baeza ◽

A. Antiñolo ◽

F. Carrillo-Hermosilla ◽

J. Tejeda ◽

...

Keyword(s):

Molecular Structure ◽

Metal Complexes ◽

Spectroscopic Characterization ◽

X Ray ◽

Group 4 ◽

Group 4 Metal

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Monomeric, Four-Coordinate Group 4 Metal Complexes with Chelating Bis(tert-butylamido)cyclodisilazane Ligands: Syntheses and Molecular Structures of {(MeSiNtBu)2(NtBu)2}MCl2and {(MeSiNtBu)2(NtBu)2}MMe2, M = Zr, Hf

Inorganic Chemistry ◽

10.1021/ic970287+ ◽

1997 ◽

Vol 36 (20) ◽

pp. 4451-4457 ◽

Cited By ~ 10

Author(s):

Luke Grocholl ◽

Volker Huch ◽

Lothar Stahl ◽

Richard J. Staples ◽

Phaedra Steinhart ◽

...

Keyword(s):

Metal Complexes ◽

Molecular Structures ◽

Group 4 ◽

Coordinate Group ◽

Group 4 Metal

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ChemInform Abstract: Transformations of Functional Groups Attached to Cyclopentadienyl or Related Ligands in Group 4 Metal Complexes

ChemInform ◽

10.1002/chin.201547237 ◽

2015 ◽

Vol 46 (47) ◽

pp. no-no

Author(s):

Jiri Pinkas ◽

Martin Lamac

Keyword(s):

Metal Complexes ◽

Functional Groups ◽

Group 4 ◽

Group 4 Metal

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Novel Alkylidenating Agents via the α Lithiation of Monoalkyl Group 4 Metal Derivatives: Methylidene-Metal Complexes and Their Active Lithiated Precursors

European Journal of Organic Chemistry ◽

10.1002/ejoc.200400808 ◽

2005 ◽

Vol 2005 (6) ◽

pp. 993-997 ◽

Cited By ~ 17

Author(s):

John J. Eisch ◽

Adetenu A. Adeosun

Keyword(s):

Metal Complexes ◽

Group 4 ◽

Metal Derivatives ◽

Group 4 Metal

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NSSN-Type Group 4 Metal Complexes in the Ring-Opening Polymerization of l-Lactide

Inorganic Chemistry ◽

10.1021/acs.inorgchem.1c01056 ◽

2021 ◽

Author(s):

Salvatore Impemba ◽

Giuseppina Roviello ◽

Stefano Milione ◽

Carmine Capacchione

Keyword(s):

Metal Complexes ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Type Group ◽

Group 4 ◽

Group 4 Metal

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New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Organometallics ◽

10.1021/om0701569 ◽

2007 ◽

Vol 26 (14) ◽

pp. 3374-3384 ◽

Cited By ~ 33

Author(s):

Jong-Dae Lee ◽

Young-Joo Lee ◽

Ki-Chul Son ◽

Minserk Cheong ◽

Jaejung Ko ◽

...

Keyword(s):

Metal Complexes ◽

Structural Characterization ◽

System Synthesis ◽

Ligand System ◽

Group 4 ◽

Constrained Geometry ◽

Group 4 Metal

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Übergangsmetallkomplexe mit Schwefelliganden, LXXIII. Diastereospezifische Dichlormethylierung schwefelreicher [RuII(SRR′)(PPh3)′S4]-Komplexe (SRR′ = einzähniger Thioether- oder Thiol-Ligand; ′S4′2- = 1,2-Bis(2-mercaptophenylthio)ethan(2-)) / Transition Metal Complexes with Sulfur Ligands, LXXIII. Diastereospecific Dichloromethylation of Sulfur Rich [RuII(SRR′)(PPh3)′S4] Complexes (SRR′ = Monodentate Thioether or Thiol Ligand;′S4′2- = 1,2-Bis(2-mercaptophenylthio)ethane(2-))

Zeitschrift für Naturforschung B ◽

10.1515/znb-1991-1201 ◽

1991 ◽

Vol 46 (12) ◽

pp. 1585-1592 ◽

Cited By ~ 3

Author(s):

Dieter Sellmann ◽

Peter Lechner ◽

Falk Knoch ◽

Matthias Moll

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Molecular Structures ◽

X Ray ◽

X Ray Crystallography ◽

Thiol Ligand

Under exclusion of air the thioether and thiol complexes [Ru(SRR′)(PPh3)′S4′] (′S4′2- = 1,2-bis(2-mercaptophenylthio)ethane (2—)) easily react with CHCl3 yielding [Ru(Cl)(PPh3)(′S4′—CHCl2)] in which one thiolato atom of the ′S4′ ligand is diastereospecifically dichloromethylated. In the presence of air, however, [RuIII(Cl)(PPh3)′S4′] is formed.The molecular structures of [Ru(Cl)(PPh3)(′S4′-CHCl2)] · 2CHCl3 and [RuIII(Cl)(PPh3)′buS4′] have been determined by X-ray crystallography. ′buS4′2- (= 1,2-bis(3,5-di(t-butyl)-2-mercaptophenylthio)ethane(2-)) is the t-butyl derivative of the ′S4′ ligand. Reasons for observed diastereospecifity of alkylation are discussed.

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Tridentate [N,N,O] Schiff-base group 4 metal complexes: Synthesis, structural characterization and reactivity in olefin polymerization

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2006.05.043 ◽

2006 ◽

Vol 258 (1-2) ◽

pp. 275-283 ◽

Cited By ~ 30

Author(s):

Gino Paolucci ◽

Alessandra Zanella ◽

Laura Sperni ◽

Valerio Bertolasi ◽

Mina Mazzeo ◽

...

Keyword(s):

Schiff Base ◽

Metal Complexes ◽

Structural Characterization ◽

Olefin Polymerization ◽

Group 4 ◽

Group 4 Metal ◽

Base Group

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Double-Dimethylsilyl-Bridged Dicyclopentadienyl Group 4 Metal Complexes. X-ray Molecular Structures of M[(Me2Si)2(.eta.5-C5H3)2]Cl2 (M = Ti, Zr) and (TiCl3)2{.mu.-[(Me2Si)2(.eta.5-C5H3)2]}

Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {Cp*HfCl2[Ph4P2N3(NH)S2]}2, Cp*ZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl

Molecular structures of the main group 4 metal(II) bis(trimethylsilyl)-amides M[N(SiMe3)2]2 in the crystal (X-ray) and vapour (gas-phase electron diffraction)

Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [Cp*ZrCl3(2-TCMP)], Cp*=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane

Monomeric, Four-Coordinate Group 4 Metal Complexes with Chelating Bis(tert-butylamido)cyclodisilazane Ligands: Syntheses and Molecular Structures of {(MeSiNtBu)2(NtBu)2}MCl2and {(MeSiNtBu)2(NtBu)2}MMe2, M = Zr, Hf

ChemInform Abstract: Transformations of Functional Groups Attached to Cyclopentadienyl or Related Ligands in Group 4 Metal Complexes

Novel Alkylidenating Agents via the α Lithiation of Monoalkyl Group 4 Metal Derivatives: Methylidene-Metal Complexes and Their Active Lithiated Precursors

NSSN-Type Group 4 Metal Complexes in the Ring-Opening Polymerization of l-Lactide

New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Tridentate [N,N,O] Schiff-base group 4 metal complexes: Synthesis, structural characterization and reactivity in olefin polymerization

Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {CpHfCl2[Ph4P2N3(NH)S2]}2, CpZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl

Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [CpZrCl3(2-TCMP)], Cp=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane