Synthesis of (1R,1'S)- and (1S,1'S),(1R,1'R)-bis[1-(diphenylphosphino)ethyl]benzene derivatives and their cyclometalation reactions with platinum(II) compounds. The x-ray crystal structures of [2,6-bis[(diphenylphosphino)methyl]phenyl]chloropalladium(II), [(1R,1'S)-2,6-bis[1-(diphenylphosphino)ethyl]phenyl]chloroplatinum(II), and [(1R,1'R),(1S,1'S)-2,6-bis[1-(diphenylphosphino)ethyl]phenyl]chloroplatinum(II)

Fabrizio Gorla; Luigi M. Venanzi; Alberto Albinati

doi:10.1021/om00013a014

Synthesis of (1R,1'S)- and (1S,1'S),(1R,1'R)-bis[1-(diphenylphosphino)ethyl]benzene derivatives and their cyclometalation reactions with platinum(II) compounds. The x-ray crystal structures of [2,6-bis[(diphenylphosphino)methyl]phenyl]chloropalladium(II), [(1R,1'S)-2,6-bis[1-(diphenylphosphino)ethyl]phenyl]chloroplatinum(II), and [(1R,1'R),(1S,1'S)-2,6-bis[1-(diphenylphosphino)ethyl]phenyl]chloroplatinum(II)

Organometallics ◽

10.1021/om00013a014 ◽

1994 ◽

Vol 13 (1) ◽

pp. 43-54 ◽

Cited By ~ 57

Author(s):

Fabrizio Gorla ◽

Luigi M. Venanzi ◽

Alberto Albinati

Keyword(s):

Crystal Structures ◽

Ethyl Benzene ◽

Benzene Derivatives ◽

X Ray ◽

Methyl Phenyl

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Synthesis, characterization and crystal structures of novel fluorinated di(thiazolyl)benzene derivatives

Organic Chemistry Frontiers ◽

10.1039/c9qo00044e ◽

2019 ◽

Vol 6 (6) ◽

pp. 780-790 ◽

Cited By ~ 6

Author(s):

Maciej Barłóg ◽

Ihor Kulai ◽

Xiaozhou Ji ◽

Nattamai Bhuvanesh ◽

Somnath Dey ◽

...

Keyword(s):

Crystal Structures ◽

Benzene Derivatives ◽

Stille Coupling ◽

X Ray ◽

X Ray Crystallography ◽

Microwave Assisted

A series of 11 novel fluorinated and non-fluorinated di(thiazolyl)benzenes have been synthesized via microwave assisted Stille coupling and characterized using X-ray crystallography.

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Synthesis and X-ray Crystal Structures of Palladium(II) and Platinum(II) Complexes of the PCP-Type Chiral Tridentate Ligand (1R,1‘R)-1,3-Bis[1-(diphenylphosphino)ethyl]benzene. Use in the Asymmetric Aldol Reaction of Methyl Isocyanoacetate and Aldehydes

Organometallics ◽

10.1021/om980461h ◽

1998 ◽

Vol 17 (20) ◽

pp. 4374-4379 ◽

Cited By ~ 144

Author(s):

James M. Longmire ◽

Xumu Zhang ◽

Maoyu Shang

Keyword(s):

Crystal Structures ◽

Aldol Reaction ◽

Tridentate Ligand ◽

Ethyl Benzene ◽

Asymmetric Aldol ◽

X Ray ◽

Asymmetric Aldol Reaction

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ChemInform Abstract: Possibility of Heptacoordination at Silicon: Synthesis and X-Ray Crystal Structures of Tris(8-(dimethylamino)naphthyl)silane and Tris(2- ((dimethylamino)methyl)phenyl)fluorosilane.

ChemInform ◽

10.1002/chin.199418174 ◽

2010 ◽

Vol 25 (18) ◽

pp. no-no

Author(s):

C. BRELIERE ◽

F. CARRE ◽

R. J. P. CORRIU ◽

G. ROYO ◽

M. WONG CHI MAN ◽

...

Keyword(s):

Crystal Structures ◽

X Ray ◽

Methyl Phenyl

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ChemInform Abstract: THE PREPARATION AND X-RAY CRYSTAL STRUCTURES OF BIS(4R-OXAZOLIDINE-4′-CARBOXYLATO)COPPER(II) (R = METHYL, PHENYL)

Chemischer Informationsdienst ◽

10.1002/chin.198545270 ◽

1985 ◽

Vol 16 (45) ◽

Author(s):

S.-B. TEO ◽

S. G. TEOH ◽

M. R. SNOW

Keyword(s):

Crystal Structures ◽

X Ray ◽

Methyl Phenyl

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Synthesis of chiral organotin reagents: synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]stannane

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/b200317c ◽

2002 ◽

pp. 1286-1296 ◽

Cited By ~ 12

Author(s):

Madeleine Helliwell ◽

Eric J. Thomas ◽

Linda A. Townsend

Keyword(s):

Crystal Structures ◽

X Ray ◽

Tin Chloride ◽

Methyl Phenyl

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Oxidative addition - reductive elimination reactions of mono- and bis(aryl)platinum(II) complexes with two amino ligands in fixed trans positions. X-ray crystal structures of (2,6-bis[[dimethylamino]methyl]phenyl)(4-tolyl)platinum(IV) diiodide and (2,6-bis[[dimethylamino]methyl]phenyl)platinum(IV) trichloride

Organometallics ◽

10.1021/om00118a003 ◽

1990 ◽

Vol 9 (4) ◽

pp. 903-912 ◽

Cited By ~ 45

Author(s):

Gerard Van Koten ◽

Johannus A. M. Van Beek ◽

Ingrid C. M. Wehman-Ooyevaar ◽

Fred Muller ◽

Casper H. Stam ◽

...

Keyword(s):

Crystal Structures ◽

Oxidative Addition ◽

Reductive Elimination ◽

X Ray ◽

Elimination Reactions ◽

Methyl Phenyl

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Possibility of heptacoordination at silicon: synthesis and X-ray crystal structures of tris[8-(dimethylamino)naphthyl]silane and tris[2-((dimethylamino)methyl)phenyl]fluorosilane

Organometallics ◽

10.1021/om00013a045 ◽

1994 ◽

Vol 13 (1) ◽

pp. 307-314 ◽

Cited By ~ 44

Author(s):

Claire Breliere ◽

Francis Carre ◽

Robert J. P. Corriu ◽

Gerard Royo ◽

Michel Wong Chi Man ◽

...

Keyword(s):

Crystal Structures ◽

X Ray ◽

Methyl Phenyl

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ChemInform Abstract: Fluxionality and Bonding in Formamidine and Formamidinate Complexes of Pt(II) and Pd(II) Containing the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand: A Proton NMR Study with X-Ray Crystal Structures of [Pt{C6H3(CH2NMe2)2-2,6}{p-MeC6H4N

Chemischer Informationsdienst ◽

10.1002/chin.198632284 ◽

1986 ◽

Vol 17 (32) ◽

Author(s):

D. M. GROVE ◽

G. VAN KOTEN ◽

H. J. C. UBBELS ◽

K. VRIEZE ◽

L. C. NIEMANN ◽

...

Keyword(s):

Crystal Structures ◽

Proton Nmr ◽

X Ray ◽

Nmr Study ◽

Methyl Phenyl

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Reactivity of [2,6-Bis((dimethylamino)methyl)phenyl]gold(I), an Unusual Intermolecularly Stabilized Bis(amino)aryl−Gold(I) Dimer, toward Alkyl Halides. X-ray Crystal Structures of Its Iodomethane and Methylene Diiodide Adducts†

Organometallics ◽

10.1021/om991043v ◽

2000 ◽

Vol 19 (17) ◽

pp. 3288-3295 ◽

Cited By ~ 15

Author(s):

María Contel ◽

Dominique Nobel ◽

Anthony L. Spek ◽

Gerard van Koten

Keyword(s):

Crystal Structures ◽

Alkyl Halides ◽

X Ray ◽

Methyl Phenyl

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Stereoselective Methylation of 1-(Diphenylphosphanyl)-2-[(methoxycarbonyl)methyl]ferrocene. The Crystal Structures of the Methylated Ester and Its Palladium(II) Complex with an Auxiliary 2-[(Dimethylamino)methyl]phenyl Ligand.

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc20070985 ◽

2007 ◽

Vol 72 (8) ◽

pp. 985-995 ◽

Cited By ~ 6

Author(s):

Martin Lamač ◽

Ivana Císařová ◽

Petr Štěpnička

Keyword(s):

Carboxylic Acid ◽

Carbon Atom ◽

Single Crystal ◽

Crystal Structures ◽

Methyl Iodide ◽

X Ray Diffraction ◽

X Ray ◽

Chiral Carbon ◽

Hydrolysis Of ◽

Methyl Phenyl

Treatment of racemic 1-(diphenylphosphanyl)-2-[(methoxycarbonyl)methyl]ferrocene successively with NaN(SiMe3)2 and methyl iodide affords the C-alkylated product, 1-(diphenylphosphanyl)-2-[1-(methoxycarbonyl)ethyl]ferrocene (6), as a mixture of diastereoisomers in ca. 10:1 ratio, from which the major (S,Rp/R,Sp)-diastereoisomer is easily isolated by crystallisation. (S,Rp/R,Sp)-6 reacts with [Pd(LNC)(MeCN)2]ClO4 (LNC = 2-[(dimethylamino-κN)- methyl]phenyl-κC1) to give the cationic bis-chelate complex (S,Rp/R,Sp)-[Pd(LNC)(6-κ2O,P)]- ClO4 (9). The structures of (S,Rp/R,Sp)-6 and 9 have been determined by single-crystal X-ray diffraction. Hydrolysis of ester 6 to the corresponding carboxylic acid proved to be difficult, being complicated by racemisation at the chiral carbon atom and oxidation of the phosphanyl group.

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