Use of the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand for the Study of Nucleophilic Substitution at Hexacoordinate Silicon Centers. Evidence Suggestive of a Heptacoordinate Silicon Transition State

Francis Carre; Claude Chuit; Robert J. P. Corriu; Alan Fanta; Ahmad Mehdi; Catherine Reye

doi:10.1021/om00001a030

Use of the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand for the Study of Nucleophilic Substitution at Hexacoordinate Silicon Centers. Evidence Suggestive of a Heptacoordinate Silicon Transition State

Organometallics ◽

10.1021/om00001a030 ◽

1995 ◽

Vol 14 (1) ◽

pp. 194-198 ◽

Cited By ~ 32

Author(s):

Francis Carre ◽

Claude Chuit ◽

Robert J. P. Corriu ◽

Alan Fanta ◽

Ahmad Mehdi ◽

...

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

Methyl Phenyl

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ChemInform Abstract: Group Transfers. Part 1. Enolate Structures Contributing to the Transition State for Nucleophilic Substitution on α-Substituted Carbonyl Compounds.

ChemInform ◽

10.1002/chin.198803085 ◽

1988 ◽

Vol 19 (3) ◽

Author(s):

T. I. YOUSAF ◽

E. S. LEWIS

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

Carbonyl Compounds ◽

Abstract Group

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Structure-reactivity cross correlations in nucleophilic substitution: Isoparametricity and transition-state structure

Theoretical and Experimental Chemistry ◽

10.1007/bf02511491 ◽

1999 ◽

Vol 35 (2) ◽

pp. 63-74 ◽

Cited By ~ 4

Author(s):

I. V. Shpan'ko

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

State Structure ◽

Transition State Structure ◽

Cross Correlations

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Bimolecular nucleophilic substitution at a resonance-stabilized carbenium ion: Elevated value of cross-interaction constant, imbalanced transition state and the non-interactive phenomenon

Journal of Physical Organic Chemistry ◽

10.1002/poc.610070810 ◽

1994 ◽

Vol 7 (8) ◽

pp. 448-454 ◽

Cited By ~ 1

Author(s):

Ikchoon Lee

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

Interaction Constant ◽

Carbenium Ion

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ChemInform Abstract: Nucleophilic Substitution of Benzyl Benzenesulphonates with Anilines in Methanol-Acetonitrile Mixtures. Part 2. Variation in Transition-State Structure.

ChemInform ◽

10.1002/chin.198708097 ◽

1987 ◽

Vol 18 (8) ◽

Author(s):

I. LEE ◽

S. C. SOHN ◽

C. H. KANG ◽

Y. J. OH

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

State Structure ◽

Transition State Structure

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ChemInform Abstract: Cross-Interaction Constants as a Measure of the Transition-State Structure. Part 1. The Degree of Bond Formation in Nucleophilic Substitution Reactions

ChemInform ◽

10.1002/chin.198909076 ◽

1989 ◽

Vol 20 (9) ◽

Author(s):

I. LEE ◽

C. S. SHIM ◽

S. Y. CHUNG ◽

H. Y. KIM ◽

H. W. LEE

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

Bond Formation ◽

State Structure ◽

Transition State Structure ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions

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Kinetic Study on Nucleophilic Substitution Reaction of 5-Nitro-8-quinolyl Benzoate, Picolinate, Nicotinate and Isonicotinate with Alkali Metal Ethoxide: Effect of Nonleaving Group on Reactivity and Transition State Structure

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2014.35.6.1789 ◽

2014 ◽

Vol 35 (6) ◽

pp. 1789-1793

Author(s):

Jieun Lee ◽

Min-Young Kim ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Transition State ◽

Kinetic Study ◽

Nucleophilic Substitution ◽

Substitution Reaction ◽

Nucleophilic Substitution Reaction ◽

State Structure ◽

Transition State Structure

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Principles of Nucleophilic Substitution

International Journal of Recent Advances in Science and Technology ◽

10.30750/ijarst.534 ◽

2018 ◽

Vol 5 (3) ◽

Cited By ~ 1

Author(s):

Dr. Aliakbar Muhamdi Ameri

Keyword(s):

Transition State ◽

Nucleophilic Substitution ◽

Substitution Reaction ◽

Theoretical Paper

The work reported in this theoretical paper deals with types of substitution reaction ( sn1 , sn2 , conditions of both reactions , methods of both reactions , diagram of reactions , energy for reactions, types of reactants , products, rate of reactions , steps of reactions, transition state for reaction) and other reactions.

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